Photocatalytic CO2 conversion to CO

Table of all the experiments that have a turnover number for CO greater than 100, sorted by catalyst and in descending order.

TON CO > 100

Table of all the experiments that have a turnover number for CO less than 100, sorted by catalyst.

TON CO < 100

Literature

[DSP19] Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO₂ or CO to CH₄. Hunter Shirley, Xiaojun Su, Harshin Sanjanwala, Kallol Talukdar, Jonah W. Jurss, Jared H. Delcamp, Journal of the American Chemical Society 2019, Vol. 141, Pages 6617-6622. DOI2: 10.1021/jacs.9b00937
Publication: Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4

[Vld17] Visible-light-driven methane formation from CO2 with a molecular iron catalyst. Heng Rao, Luciana C. Schmidt, Julien Bonin, Marc Robert, Nature 2017, Vol. 548, Pages 74-77. DOI2: 10.1038/nature23016
Publication: Visible-light-driven methane formation from CO2 with a molecular iron catalyst

[TVL18] Toward Visible-Light Photochemical CO₂-to-CH₄ Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis. Heng Rao, Julien Bonin, Marc Robert, The Journal of Physical Chemistry C 2018, Vol. 122, Pages 13834-13839. DOI2: 10.1021/acs.jpcc.8b00950
Publication: Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis

[VLD18] Visible-Light-Driven Conversion of CO₂ to CH₄ with an Organic Sensitizer and an Iron Porphyrin Catalyst. Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert, Journal of the American Chemical Society 2018, Vol. 140, Pages 17830-17834. DOI2: 10.1021/jacs.8b09740
Publication: Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst

[PRo15] Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light. Alonso Rosas-Hernández, Henrik Junge, Matthias Beller, ChemCatChem 2015, Vol. 7, Pages 3316-3321. DOI2: 10.1002/cctc.201500494
Publication: Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light

[Rtr16] Rhenium(i) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO₂ reduction. Jana Rohacova, Osamu Ishitani, Chemical Science 2016, Vol. 7, Pages 6728-6739. DOI2: 10.1039/c6sc01913g
Publication: Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction

[PRD18] Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO ₂ Photoreduction. Thibault Fogeron, Pascal Retailleau, Lise‐Marie Chamoreau, Yun Li, Marc Fontecave, Angewandte Chemie International Edition 2018, Vol. 57, Pages 17033-17037. DOI2: 10.1002/anie.201809084
Publication: Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction

[PpC21] Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore. Huiqing Yuan, Banggui Cheng, Jingxiang Lei, Long Jiang, Zhiji Han, Nature Communications 2021, Vol. 12. DOI2: 10.1038/s41467-021-21923-9
Publication: Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore

[SaE14] Selective and Efficient Photocatalytic CO₂ Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst. Julien Bonin, Marc Robert, Mathilde Routier, Journal of the American Chemical Society 2014, Vol. 136, Pages 16768-16771. DOI2: 10.1021/ja510290t
Publication: Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst

[Mcm17] Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH. Matthew Stanbury, Jean-Daniel Compain, Monica Trejo, Parker Smith, Eric Gouré, Sylvie Chardon-Noblat, Electrochimica Acta 2017, Vol. 240, Pages 288-299. DOI2: 10.1016/j.electacta.2017.04.080
Publication: Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH

[FIR18] Function-Integrated Ru Catalyst for Photochemical CO₂ Reduction. Sze Koon Lee, Mio Kondo, Masaya Okamura, Takafumi Enomoto, Go Nakamura, Shigeyuki Masaoka, Journal of the American Chemical Society 2018, Vol. 140, Pages 16899-16903. DOI2: 10.1021/jacs.8b09933
Publication: Function-Integrated Ru Catalyst for Photochemical CO2 Reduction

[PRo16] Photocatalytic Reduction of Carbon Dioxide to CO and HCO₂H Using fac-Mn(CN)(bpy)(CO)₃. Po Ling Cheung, Charles W. Machan, Aramice Y. S. Malkhasian, Jay Agarwal, Clifford P. Kubiak, Inorganic Chemistry 2016, Vol. 55, Pages 3192-3198. DOI2: 10.1021/acs.inorgchem.6b00379
Publication: Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3

[PCr14] Photocatalytic CO₂reduction using a Mn complex as a catalyst. Hiroyuki Takeda, Hiroki Koizumi, Kouhei Okamoto, Osamu Ishitani, Chem. Commun. 2014, Vol. 50, Pages 1491-1493. DOI2: 10.1039/c3cc48122k
Publication: Photocatalytic CO2 reduction using a Mn complex as a catalyst

[Vld16] Visible light driven reduction of CO 2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer. Jun-Xiao Zhang, Chang-Ying Hu, Wei Wang, Hui Wang, Zhao-Yong Bian, Applied Catalysis A: General 2016, Vol. 522, Pages 145-151. DOI2: 10.1016/j.apcata.2016.04.035
Publication: Visible light driven reduction of CO2 catalyzed by an abundant manganese catalyst with zinc porphyrin photosensitizer

[HEa18] Highly Efficient and Robust Photocatalytic Systems for CO₂ Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts. Hiroyuki Takeda, Hiroko Kamiyama, Kouhei Okamoto, Mina Irimajiri, Toshihide Mizutani, Kazuhide Koike, Akiko Sekine, Osamu Ishitani, Journal of the American Chemical Society 2018, Vol. 140, Pages 17241-17254. DOI2: 10.1021/jacs.8b10619
Publication: Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts

[Itb17] [Ir(tpy)(bpy)Cl] as a Photocatalyst for CO₂ Reduction under Visible-Light Irradiation. Shunsuke Sato, Takeshi Morikawa, ChemPhotoChem 2017, Vol. 2, Pages 207-212. DOI2: 10.1002/cptc.201700133
Publication: Ir(tpy)(bpy)Cl as a Photocatalyst for CO2 Reduction under Visible-Light Irradiation

[HEa16] Highly Efficient and Selective Photocatalytic CO₂ Reduction by Iron and Cobalt Quaterpyridine Complexes. Zhenguo Guo, Siwei Cheng, Claudio Cometto, Elodie Anxolabéhère-Mallart, Siu-Mui Ng, Chi-Chiu Ko, Guijian Liu, Lingjing Chen, Marc Robert, Tai-Chu Lau, Journal of the American Chemical Society 2016, Vol. 138, Pages 9413-9416. DOI2: 10.1021/jacs.6b06002
Publication: Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes

[PSC22] Phenoxazine‐Sensitized CO ₂ ‐to‐CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties‐Catalytic Performance Study. Martin Kientz, Grace Lowe, Blaine G. McCarthy, Garret M. Miyake, Julien Bonin, Marc Robert, ChemPhotoChem 2022, Vol. 6. DOI2: 10.1002/cptc.202200009
Publication: Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study

[Nip18] Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction. Dalton B. Burks, Shakeyia Davis, Robert W. Lamb, Xuan Liu, Roberta R. Rodrigues, Nalaka P. Liyanage, Yujie Sun, Charles Edwin Webster, Jared H. Delcamp, Elizabeth T. Papish, Chemical Communications 2018, Vol. 54, Pages 3819-3822. DOI2: 10.1039/c7cc09507d
Publication: Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction

[VLD17] Visible-Light-Driven Photocatalytic CO₂ Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production. Dachao Hong, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Takahiko Kojima, Journal of the American Chemical Society 2017, Vol. 139, Pages 6538-6541. DOI2: 10.1021/jacs.7b01956
Publication: Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production

[EtF21] Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re ₂ Cl ₂ Complex Assisted by Various Photosensitizers. Robin Giereth, Martin Obermeier, Lukas Forschner, Michael Karnahl, Matthias Schwalbe, Stefanie Tschierlei, ChemPhotoChem 2021, Vol. 5, Pages 644-653. DOI2: 10.1002/cptc.202100034
Publication: Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers

[PRo22] Photocatalytic Reduction of CO₂by Highly Efficient Homogeneous Fe^IICatalyst based on 2,6‐Bis(1’,2’,3’‐triazolyl‐methyl)pyridine. Comparison with Analogues.. Lisa‐Lou Gracia, Elham Barani, Jonas Braun, Anthony B. Carter, Olaf Fuhr, Annie K. Powell, Karin Fink, Claudia Bizzarri, ChemCatChem 2022, Vol. 14. DOI2: 10.1002/cctc.202201163
Publication: Photocatalytic Reduction of CO2 by Highly Efficient Homogeneous FeII Catalyst based on 2,6-Bis(1’,2’,3’-triazolyl-methyl)pyridine. Comparison with Analogues.

[ECD22] Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO₂ Reduction. Patricia De La Torre, Jeffrey S. Derrick, Andrew Snider, Peter T. Smith, Matthias Loipersberger, Martin Head-Gordon, Christopher J. Chang, ACS Catalysis 2022, Vol. 12, Pages 8484-8493. DOI2: 10.1021/acscatal.2c02072
Publication: Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2	lit
1.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		130000	29000	4900000	[DSP19]
2.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	175000	19000	29000	[DSP19]
3.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	51000	12000		[DSP19]
4.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	8000	5000	34000	[DSP19]
5.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	108000	4000	278000	[DSP19]
6.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		5000	1000	15000	[DSP19]
7.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		367	79	26	[Vld17]
8.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	240	66	73	[Vld17]
9.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		178	32	103	[TVL18]
10.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		198	31	24	[Vld17]
11.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		198	31	24	[TVL18]
12.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF	TFE	140	29	23	[VLD18]
13.	Fe(DHPP)Cl	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		139	26	15	[Vld17]
14.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		151	24	77	[TVL18]
15.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		134	23	67	[TVL18]

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2	TON HCOOH	lit
1.	Ru(bpy)2CO3	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		3		11	39	[PRo15]
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		2		4	21	[PRo15]
3.	Ru(bpy)2CO3	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		3		11	39	[PRo15]
4.	Ru(bpy)2CO3	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		2		4	21	[PRo15]
5.	Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05			DMF		20		72	290	[Rtr16]
6.	Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05	BI(OH)H	0.03	DMF		16		49	280	[Rtr16]
7.	[K]2[MoO(Hqpdt)2]	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN		13		51	31	[PRD18]
8.	[MoO(2Hqpdt)2][NBu4]	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN		40		89	83	[PRD18]
9.	[MoO(qpdt)2][NBu4]2	0.05	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN		73		670	80	[PRD18]
10.	Fe(DHPP)Cl	0.0002	purpurin	0.1	BIH	0.01	DMF		88		0		[PpC21]
11.	Fe(DHPP)Cl	0	[Cu(PP)2][TBA]2	0.1	BIH	0.1	DMF		4.4		0		[PpC21]
12.	Fe(DHPP)Cl	0.002	Molecule:100936	0.2	TEA	0.05	MeCN		60				[SaE14]
13.	Mn(phdk)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	DMF		21			22	[Mcm17]
14.	Mn(phdk)(CO)3Br		Ru(bpy)3Cl2	100			DMF		9			13	[Mcm17]
15.	Mn(phdk)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		8			52	[Mcm17]
16.	Mn(phdk)(CO)3(MeCN)	2	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		5			18	[Mcm17]
17.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		15			58	[Mcm17]
18.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	200	BNAH	0.1	MeCN		8			52	[Mcm17]
19.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		9			48	[Mcm17]
20.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		7			40	[Mcm17]
21.	Mn(phdk)(CO)3(MeCN)		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		7			34	[Mcm17]
22.	Ru(dppq)(tpy)(MeCN)	0.04			BIH	0.1	DMA		58		1	3	[FIR18]
23.	Mn(phen)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	DMF		17			4	[Mcm17]
24.	Mn(CN)(bpy)(CO)3	0.1	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	MeCN		19		1.4	8.1	[PRo16]
25.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	MeCN		3.4		0.14		[PRo16]
26.	Mn(CN)(bpy)(CO)3		[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		0.6		1.2	0.72	[PRo16]
27.	Mn(CN)(bpy)(CO)3	1	[Ru(dmb)3][PF6]2	1	BNAH	0.1	DMF		0.83		0.0073	5.2	[PRo16]
28.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF	Argon gas	1.5		7.8	3.8	[PRo16]
29.	Mn(CN)(bpy)(CO)3	0.1	[Ru(dmb)3][PF6]2	1	BNAH	0.1	MeCN		21		1.3	9	[PRo16]
30.	Mn(CN)(bpy)(CO)3	0.1	[Ru(dmb)3][PF6]2	0.1	BNAH	0.1	DMF		3.9		0.64	36	[PRo16]
31.	Mn(CN)(bpy)(CO)3	1	[Ru(dmb)3][PF6]2	1	BNAH	0.1	MeCN		3.1		0.14		[PRo16]
32.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		2.2				[PRo16]
33.	Mn(CN)(bpy)(CO)3	0.1	[Ru(dmb)3][PF6]2	0.1	BNAH	0.1	MeCN		7.9		0.56	4.5	[PRo16]
34.	Mn(CN)(bpy)(CO)3		[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF	Argon gas	0.87		1.3	3.2	[PRo16]
35.	Mn(CN)(bpy)(CO)3	1	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	MeCN		4.2		0.8	1.4	[PRo16]
36.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		3.2		0.45	21	[PRo16]
37.	Mn(CN)(bpy)(CO)3	0.1	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		9.1		1.2	130	[PRo16]
38.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF	Argon gas	2.2		4.4	0.55	[PRo16]
39.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	MeCN		5.9		0.24	2.1	[PRo16]
40.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2		BNAH	0.1	DMF	Argon gas	2.3			2.2	[PRo16]
41.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2		BNAH	0.1	DMF		2.1			1.9	[PRo16]
42.	Mn(CN)(bpy)(CO)3	1	[Ru(dmb)3][PF6]2	1	BNAH	0.1	DMF		2.3		0.37	9.5	[PRo16]
43.	Mn(CN)(bpy)(CO)3	0.1	[Ru(dmb)3][PF6]2	1	BNAH	0.1	DMF		7.1		1.6	130	[PRo16]
44.	Mn(CN)(bpy)(CO)3	1	[Ru(dmb)3][PF6]2	1	BNAH	0.1	MeCN		3.2		0.17	1.2	[PRo16]
45.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF	Argon gas	2.4		1.4		[PRo16]
46.	Mn(CN)(bpy)(CO)3		[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		1.5		2.8	5.7	[PRo16]
47.	Mn(CN)(bpy)(CO)3	0.1	[Ru(dmb)3][PF6]2	0.1	BNAH	0.1	DMF		2.8		0.2	16	[PRo16]
48.	Mn(CN)(bpy)(CO)3	1	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		3		0.24	5.8	[PRo16]
49.	Mn(CN)(bpy)(CO)3	0.1	[Ru(dmb)3][PF6]2	0.1	BNAH	0.1	MeCN		4.7		0.27		[PRo16]
50.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2		BNAH	0.1	DMF		2				[PRo16]
51.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		5.8		0.26		[PRo16]
52.	Mn(CN)(bpy)(CO)3	0.5	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		0.92		0.25	11	[PRo16]
53.	Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1	DMA		9		14	98	[PCr14]
54.	Mn(bpy)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	DMF		6			39	[Mcm17]
55.	Mn(bpy)(CO)3Br	0.5			TEA	0.1	MeCN		2			1	[Vld16]
56.	Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1	MeCN		40		17	78	[PCr14]
57.	Mn(bpy)(CO)3Br	1.5	ZnTPP	0.5	TEA	0.1	MeCN		97			18	[Vld16]
58.	Mn(bpy)(CO)3Br	0.05	Ru(bpy)3	0.05	BNAH	0.1	DMF		12		8	157	[PCr14]
59.	Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1	DMF		8		1	67	[PCr14]
60.	Mn(bpy)(CO)3Br		Ru(bpy)3Cl2	100	BNAH	0.1	MeCN		47			15	[Mcm17]
61.	Mn(bpy)(CO)3Br	0.5	ZnTPP	0.25	TEA	0.1	MeCN		64			16	[Vld16]
62.	Mn(bpy)(CO)3Br	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN		50		4	157	[HEa18]
63.	Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1	DMF		12		14	149	[PCr14]
64.	Mn(bpy)(CO)3Br	0.5	ZnTPP	0.5	TEA	0.1	MeCN		12			10	[Vld16]
65.	Mn(bpy)(CO)3Br	0.05	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1	DMF	Argon gas	2		49	4	[PCr14]
66.	Mn(bpy)(CO)3Br	0.5	ZnTPP	1	TEA	0.1	MeCN		8			6	[Vld16]
67.	[Ir(bpy)(tpy)Cl][PF6]2	0.1			TEOA		MeCN		2		1	20	[Itb17]
68.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100879	0.05			DMF		32				[Rtr16]
69.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100878	0.05			DMF		98				[Rtr16]
70.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100880	0.05			DMF		11				[Rtr16]
71.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05			DMF		22				[Rtr16]
72.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100880	0.05			DMF		48				[Rtr16]
73.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05			DMF		71				[Rtr16]
74.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100879	0.05			DMF		20				[Rtr16]
75.	[Re(bpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100878	0.05			DMF		27				[Rtr16]
76.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0	BIH	0.1	DMF		0		0	24	[HEa16]
77.	[Fe(qpy)(H2O)2][ClO4]2	0.01	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	Argon atmosphere	0		0	0	[HEa16]
78.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF	Argon atmosphere	0		3	21	[HEa16]
79.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF		0		0	8	[HEa16]
80.	[Fe(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	Argon atmosphere	0		1	0	[HEa16]
81.	[Fe(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF		0		139	0	[HEa16]
82.	[Fe(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF	Argon atmosphere	0		52	88	[HEa16]
83.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.05	BIH	0.1	MeCN		0		0	0	[HEa16]
84.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.05	BIH	0.1	DMF	Argon atmosphere	0		0	8	[HEa16]
85.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	Argon atmosphere	0		1	3	[HEa16]
86.	[Fe(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.05	BIH	0.1	MeCN		0		1	0	[HEa16]
87.	[Fe(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.05	BIH	0.1	DMF		0		0	10	[HEa16]
88.	[Fe(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		0		0	0	[HEa16]
89.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	DMF	Argon atmosphere	0		54	20	[HEa16]
90.	[Fe(qpy)(H2O)2][ClO4]2	0.02	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	Argon atmosphere	0		0	0	[HEa16]
91.	[Co(qpy)(H2O)2][ClO4]2	0	purpurin	2	BIH	0.1	DMF		0		0	90	[HEa16]
92.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		0		6	1	[HEa16]
93.	[Co(qpy)(H2O)2][ClO4]2	0.05	purpurin	0	BIH	0.1	DMF		27		0	4	[HEa16]
94.	[Co(qpy)(H2O)2][ClO4]2	0.05	purpurin	2			DMF		0		0	3	[HEa16]
95.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		0		2	1	[HEa16]
96.	[Co(qpy)(H2O)2][ClO4]2	0.005	purpurin	2	BIH	0.1	DMF	Argon atmosphere	0		226	167	[HEa16]
97.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	Argon atmosphere	0		33	0	[HEa16]
98.	[Co(qpy)(H2O)2][ClO4]2	0.005	purpurin	2			DMF	Argon atmosphere	0		0	26	[HEa16]
99.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3			MeCN		0		1	1	[HEa16]
100.	[Co(qpy)(H2O)2][ClO4]2	0.05	purpurin	2	BIH	0.1	DMF	Argon atmosphere	0		78	6	[HEa16]
101.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	Argon atmosphere	0		3	1	[HEa16]
102.	Co(ClO4)2	0.05	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		33		11	1	[HEa16]
103.	Co(ClO4)2	0.05	purpurin	2	BIH	0.1	DMF		0		0	3	[HEa16]
104.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100761	0.2	BIH	0.005	MeCN	TFE	88		12		[PSC22]
105.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100764	0.2	BIH	0.005	MeCN	TFE	32		57		[PSC22]
106.	[Fe(pTMAPP)Cl][PF6]4	0.002	Molecule:100765	0.2	BIH	0.005	MeCN	TFE	89				[PSC22]
107.	Ni(4O(-)py)-(MeNHC)2Cl	0.1	Ir(ppy)3	0.1			MeCN	TEA	0.3				[Nip18]
108.	Ni(4O(-)py)-(MeNHC)2Cl	0.1	Ir(ppy)3	0.1	BIH	0.011	MeCN	N2	0.2				[Nip18]
109.	Ni(4O(-)py)-(MeNHC)2Cl	0.1	Ir(ppy)3	0.1	BIH	0.011	MeCN		1.8				[Nip18]
110.	Ni(4O(-)py)-(MeNHC)2Cl	0.1	Ir(ppy)3	0.1	BIH	0.011	MeCN	proton sponge	5.6				[Nip18]
111.	Ni(4O(-)py)-(MeNHC)2Cl	0.1	Ir(ppy)3	0.1	BIH	0.011	MeCN	TEA	10.6				[Nip18]
112.	Ni(4O(-)py)-(MeNHC)2Cl	0.1	Ir(ppy)3	0.1	BIH	0.011	MeCN	TfOH	0.9				[Nip18]
113.	Ni(4O(-)py)-(MeNHC)2Cl	0.1			BIH	0.011	MeCN	TEA	0.6				[Nip18]
114.	Ni(4O(-)py)-(MeNHC)2Cl	0.1	Ir(ppy)3	0.1	BIH	0.011	DMF	TEA	9				[Nip18]
115.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1	DMA		67		3.4		[VLD17]
116.	[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	TEOA	0.1	DMA		2.6		25.5		[VLD17]
117.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		19	3	4		[TVL18]
118.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		20	3	4		[TVL18]
119.	Fe(pTMAPP)Cl5	0.002			TEA	0.05	MeCN		33				[Vld17]
120.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF		50	8	8		[VLD18]
121.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF	TFE	71	14	10		[VLD18]
122.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		24	3	5		[TVL18]
123.	[Ni(py)-(MeNHC)2(MeCN)][PF6]2	0.1	Ir(ppy)3	0.1	BIH	0.011	DMF	TEA	0.5				[Nip18]
124.	[Ni(py)-(MeNHC)2(MeCN)][PF6]2	0.1	Ir(ppy)3	0.1	BIH	0.011	MeCN	TEA	0.1				[Nip18]
125.	[Ru(bpy)(H2O)(CO)][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		21		14	75	[PRo15]
126.	[Ru(bpy)(H2O)(CO)][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		45		65	335	[PRo15]
127.	[Ru(bpy)(H2O)(CO)][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		7		9	40	[PRo15]
128.	[Ru(bpy)(H2O)(CO)][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		45		65	335	[PRo15]
129.	[Ru(bpy)(H2O)(CO)][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		34		28	211	[PRo15]
130.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		7		9	40	[PRo15]
131.	[Ru(bpy)(H2O)(CO)][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		21		14	75	[PRo15]
132.	[Ru(bpy)(H2O)(CO)][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		34		28	211	[PRo15]
133.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		8		8	34	[PRo15]
134.	[Ru(bpy)2HCO][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		8		8	34	[PRo15]
135.	[Ru(bpy)2HCO][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		25		62	225	[PRo15]
136.	[Ru(bpy)2HCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		16		29	145	[PRo15]
137.	[Ru(bpy)2HCO][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		21		16	107	[PRo15]
138.	[Ru(bpy)2HCO][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		16		29	145	[PRo15]
139.	[Ru(bpy)2HCO][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		21		16	107	[PRo15]
140.	[Ru(bpy)2HCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		25		62	225	[PRo15]
141.	[Ru(bpy)2ClCO][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		40		67	419	[PRo15]
142.	[Ru(bpy)2ClCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		36		33	296	[PRo15]
143.	[Ru(bpy)2ClCO][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		19		19	117	[PRo15]
144.	[Ru(bpy)2ClCO][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		36		33	296	[PRo15]
145.	[Ru(bpy)2ClCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		40		67	419	[PRo15]
146.	[Ru(bpy)2ClCO][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		19		19	117	[PRo15]
147.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		13		8	62	[PRo15]
148.	[Ru(bpy)2ClCO][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		13		8	62	[PRo15]
149.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05			BIH	0.01	DMF	TEA	63				[EtF21]
150.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	TEA	0.36	DMF		52				[EtF21]
151.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.005	DMF	TEA	78				[EtF21]
152.	Ru(bpy)2Cl2	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		3		9	26	[PRo15]
153.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		1		2	13	[PRo15]
154.	Ru(bpy)2Cl2	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		1		2	13	[PRo15]
155.	Ru(bpy)2Cl2	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		3		9	26	[PRo15]
156.	[Ir(dmbpy)(tpy)Cl][PF6]2	0.1			TEOA		MeCN		5		3	9	[Itb17]
157.	[Ir(dnbpy)(tpy)Cl][PF6]2	0.1			TEOA		MeCN		3		1	5	[Itb17]
158.	Molecule:100869	0.1			TEOA		MeCN		0		1	7	[Itb17]
159.	[Mn(dtBubpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05			DMF		32			85	[Rtr16]
160.	[Mn(dtBubpy)(CO)3(MeCN)][PF6]	0.05	Molecule:100877	0.05	BI(OH)H	0.03	DMF		80			60	[Rtr16]
161.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		3		4	27	[PRo15]
162.	[Ru(bpy)(AcMe)2][PF6]	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		4		12	64	[PRo15]
163.	[Ru(bpy)(AcMe)2][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		4		44	75	[PRo15]
164.	[Ru(bpy)(AcMe)2][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		3		4	27	[PRo15]
165.	[Ru(bpy)(AcMe)2][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		4		44	75	[PRo15]
166.	[Ru(bpy)(AcMe)2][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		4		12	64	[PRo15]
167.	Molecule:100941	0.1	Molecule:100940	1	BIH	0.1	MeCN		80		33		[PRo22]
168.	Molecule:100941	0.1	Molecule:100940	1	BIH	0.02	MeCN		3.2		1.6		[PRo22]
169.	Molecule:100941	0.1	Molecule:100940	1	BIH	0.02	MeCN		100		43		[PRo22]
170.	Molecule:100941	0.1			BIH	0.02	MeCN		0		0		[PRo22]
171.	Molecule:100941	0.1	Molecule:100940	1	BIH	0.02	MeCN		0		0		[PRo22]
172.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN		6		0		[ECD22]
173.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN	Ar	0		222		[ECD22]
174.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN		6		0		[ECD22]
175.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN	Ar	0		222		[ECD22]

Photocatalytic CO2 conversion to CO

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