Photocatalytic Carbon Dioxide Reduction Using Nickel Complexes as Catalysts

Review

[PCD21]

References

Catalyst #	Catalyst Molecule	#	Literature reference	Comment
1	Ni(cyclam)Cl2	10	J. L. Grant, K. Goswami, L. O. Spreer, J. W. Otovos, M. Calvin, J. Chem. Soc. Dalton Trans. 1987, 2105–2109.	old
2	[Ru(phen)2(phen-cyclam)Ni(H2O)2][ClO4]4	11	E. Kimura, X. Bu, M. Shionoya, S. Wada, S. Maruyama, Inorg. Chem. 1992, 31, 4542–4546.	old
3	[Ni(cyclam-trzbpy)Ru(bpy)2][PF6]4	12	C. Herrero, A. Quaranta, S. El Ghachtouli, B. Vauzeilles, W. Leibl, A. Aukauloo, Phys. Chem. Chem. Phys. 2014, 16, 12067–12072.
4	[Ni(dMecyclam)]2[TfO]4	14	K. Mochizuki, S. Manaka, I. Takeda, T. Kondo, Inorg. Chem. 1996, 35, 5132–5136.	old
5	Collection 100632	15	M. F. Kuehnel, K. L. Orchard, K. E. Dalle, E. Reisner, J. Am. Chem. Soc. 2017, 139, 7217–7223.	Collection incomplete
6	[Ni(tpy)2][PF6]2	16	Z. Chen, Y. Hu, J. Wang, Q. Shen, Y. Zhang, C. Ding, Y. Bai, G. Jiang, Z. Li, N. Gaponik, Chem. Mater. 2020, 32, 1517–1525.	crystalline PS (perovskite NC)
7	[Ni(bpy)3][ClO4]2	17	N. Komatsuzaki, Y. Himeda, T. Hirose, H. Sugihara, K. Kasuga, Bull. Chem. Soc. Jpn. 1999, 72, 725–731.	old
7	Ni(bpy)3Cl2	18	J. Lin, B. Qin, Z. Fang, Catal. Lett. 2019, 149, 25–33.	crystalline PS (CdS)
8	[Ru(bpy)2(phen-Et-phen)Ni(bpy)2][ClO4]4	17	N. Komatsuzaki, Y. Himeda, T. Hirose, H. Sugihara, K. Kasuga, Bull. Chem. Soc. Jpn. 1999, 72, 725–731.	old
9	[Ni(bimiqpr)][PF6]2	20	V. S. Thoi, N. Kornienko, C. G. Margarit, P. Yang, C. J. Chang, J. Am. Chem. Soc. 2013, 135, 14413–14424.
10b	Ni(4O(-)py)-(MeNHC)2Cl	21	D. B. Burks, S. Davis, R. W. Lamb, X. Liu, R. R. Rodrigues, N. P. Liyanage, Y. Sun, C. E. Webster, J. H. Delcamp, E. T. Papish, Chem. Commun. 2018, 54, 3819–3822.
11	[Ni(bpy)-(MeNHC)2][PF6]2	22	H. Shirley, X. Su, H. Sanjanwala, K. Talukdar, J. W. Jurss, J. H. Delcamp, J. Am. Chem. Soc. 2019, 141, 6617–6622.
12	[Ni(bpy-bNHCEt)][PF6]2	22	H. Shirley, X. Su, H. Sanjanwala, K. Talukdar, J. W. Jurss, J. H. Delcamp, J. Am. Chem. Soc. 2019, 141, 6617–6622.
13	[Ni(bpy-bNHCMe)][PF6]2	22	H. Shirley, X. Su, H. Sanjanwala, K. Talukdar, J. W. Jurss, J. H. Delcamp, J. Am. Chem. Soc. 2019, 141, 6617–6622.
14	[Ni(bpet)(MeCN)2][ClO4]2	26	D. Hong, Y. Tsukakoshi, H. Kotani, T. Ishizuka, T. Kojima, J. Am. Chem. Soc. 2017, 139, 6538–6541.
15	[Ni(bpet-py2)(H2O)2][ClO4]2	35	D. Hong, T. Kawanishi, Y. Tsukakoshi, H. Kotani, T. Ishizuka, T. Kojima, J. Am. Chem. Soc. 2019, 141, 20309–20317. D. Hong, T. Kawanishi, Y. Tsukakoshi, H. Kotani, T. Ishizuka, T. Kojima, J. Am. Chem. Soc. 2020, 142, 10229.	Mg2+ ions??
16	gigantic hexagonal cluster	36	W.-P. Chen, P.-Q. Liao, P.-B. Jin, L. Zhang, B.-K. Ling, S.-C. Wang, Y.-T. Chan, X.-M. Chen, Y.-Z. Zheng, J. Am. Chem. Soc. 2020, 142, 4663–4670.	Cat. undrawable
17	Ni(pbi)(pyS)2	37	S. E. Lee, A. Nasirian, Y. E. Kim, P. T. Fard, Y. Kim, B. Jeong, S.-J. Kim, J.-O. Baeg, J. Kim, J. Am. Chem. Soc. 2020, 142, 19142–19149.
18	Ni(pbt)(pyS)2	37	S. E. Lee, A. Nasirian, Y. E. Kim, P. T. Fard, Y. Kim, B. Jeong, S.-J. Kim, J.-O. Baeg, J. Kim, J. Am. Chem. Soc. 2020, 142, 19142–19149.

Catalysts

Ni(cyclam)Cl2 [Ru(phen)2(phen-cyclam)Ni(H2O)2][ClO4]4 [Ni(dMecyclam)]2[TfO]4 100632 [Show R-Groups] [Ni(tpy)2][PF6]2 [Ni(bpy)3][ClO4]2 Ni(bpy)3Cl2 [Ru(bpy)2(phen-Et-phen)Ni(bpy)2][ClO4]4 [Ni(bpet-py2)(H2O)2][ClO4]2

Photosensitizer

[Ru(phen)3][PF6]2 Red 21