Table 1
From ChemWiki
< Dinuclear Metal Synergistic Catalysis Boosts Photochemical CO2-to-CO Conversion
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.025 | 0.4 | 0.3 |
|
|
4:1 | CO2 | 1 | 25 | 450 | 10 | 65000 | 108 | n/a |
|
in 5 mL solvent | Yes | |||||||||||||||||||||||
| 0.025 | 0.4 | 0.3 |
|
|
4:1 | CO2 | 1 | 25 | 450 | 10 | 17000 | 28.2 | n/a |
|
in 5 mL solvent | No | |||||||||||||||||||||||
| 0.025 | 0.4 | 0.3 |
|
|
4:1 | CO2 | 1 | 25 | 450 | 10 | 3400 | 5.58 | n/a |
|
in 5 mL solvent | No | |||||||||||||||||||||||
| 0.025 | 0.4 | 0.3 |
|
|
4:1 | CO2 | 1 | 25 | 450 | 10 | 1500 | 2.4 | n/a |
|
in 5 mL solvent | No | |||||||||||||||||||||||
| 0.025 | 0.4 | 0.3 |
|
|
4:1 | CO2 | 1 | 25 | 450 | 10 | 0 | 0 | n/a |
|
in 5 mL solvent | No |
