Table 2

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100993	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2		1		25	450	10	65000	108														n/a		in 5 mL solvent	false
		[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2		1		25	450	10	0	0														n/a		in 5 mL solvent	false
Molecule:100993	0.025			TEOA	0.3			MeCN	H2O		4:1			CO2		1		25	450	10	0	0														n/a		in 5 mL solvent	false
Molecule:100993	0.025	[Ru(phen)3][PF6]2	0.4					MeCN	H2O		4:1			CO2		1		25	450	10	0	0														n/a		in 5 mL solvent	false
Molecule:100993	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2				25			0	0														n/a		in 5 mL solvent	false
Molecule:100993	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN						CO2		1		25	450	10	0	0														n/a		in 5 mL solvent	false
Molecule:100993	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1	Hg		CO2		1		25	450	10	64000	102														n/a		in 5 mL solvent + 0.5 mL Hg	false