Homogeneous photocatalytic CO2 conversion

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The content of this topic page covers information on molecules that have been shown to be suitable for the reduction of CO₂. Currently, the information on this page is limited to information on the conversion of CO2 to CO, CH4 and CHOOH, further extension of the content is planned in the future.

-> CO2 conversion

-> -> Photocatalytic CO2 conversion

Dear reader, I am a test molecule called phenol PhOH (100617), you can call me also benzenol PhOH (100617).

TON CO >100, sorted by catalyst - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON CH4	TON H2	TON HCOOH
1.	Fe(DHPP)Cl	0.2	[Cu(PP)2][TBA]2	0.1	BIH	0.01	DMF	>400	4779		270
2.	Fe(DHPP)Cl	2	Ir(ppy)3	0.2	TEA	0.05	MeCN	> 420	139	26	15
3.	Fe(DHPP)Cl	0.2	[Cu(PP)2][TBA]2	0.1	BIH	0.1	DMF	>400	16109		843
4.	Fe(DHPP)Cl	2	Ir(ppy)3	0.2	TEA	0.36	MeCN		140
5.	Fe(DHPP)Cl	0.6	Molecule:100932	0.02	BIH	0.06	DMF	>400	21616
6.	Mn(oMesbpy)(CO)2Br	50	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN	436	208		0.5	5
7.	Mn(bpy)(CO)3Br	2000	ZnTPP	0.5	TEA	0.1	MeCN	xenon lamp	119			19
8.	[Ir(mesbpy-(PCy2)2)][BPh4]	20			BIH	0.2	DMA	>400	470		15	2080
9.	[Co(pabop)][ClO4]2	50	Ir(ppy)3	0.2	TEA		MeCN	>460	270
10.	Molecule:100776	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN	450 nm (LED, 100 mW.cm^-2)	16896		368
11.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	3844		118	534
12.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF	460 (LED)	520		0	14
13.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	1879		15	48
14.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.05	BIH	0.1	DMF	460 (LED)	520		0	21
15.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.05	BIH	0.1	MeCN	460 (LED)	1336		10	34
16.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF	460 (LED)	1365		0	115
17.	[Fe(qpy)(H2O)2][ClO4]2	20	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	2660		29	51
18.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.2			MeCN	460 (LED)	160		8	22
19.	[Fe(qpy)(H2O)2][ClO4]2	10	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	3087		121	35
20.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.2	BIH	0.1	DMF	460 (LED)	350		1	23
21.	[Co(qpy)(H2O)2][ClO4]2	5	purpurin	2	BIH	0.1	DMF	460 (LED)	790		11	78
22.	[Co(qpy)(H2O)2][ClO4]2	50	purpurin	2	BIH	0.1	DMF	460 (LED)	197		1	9
23.	[Co(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	366		15	4
24.	[Co(qpy)(H2O)2][ClO4]2	200	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	460 (LED)	1262		7	23
further results hidden...

TON HCOOH, descending order - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ni(pbi)(pyS)2	4	Eosin Y	2	TEOA	0.4	H2O				14000
2.	Ni(pbt)(pyS)2	4	Eosin Y	2	TEOA	0.4	H2O				13100
3.	[Ru(bpy)(py)-(MeNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	300	1897	5634
4.	[Ru(bpy)(py)-(MeNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	224	1438	4593
5.	[Ru(bpy)(py)-(tBuNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	129	505	3792
6.	[Ru(bpy)(py)-(tBuNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	129	556	3296
7.	[Re(bpy)2(CO)2][OTf]	10	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		375	2750
8.	[Ir(mesbpy-(PCy2)2)][BPh4]	20			BIH	0.2	DMA	>400	470	15	2080
9.	[Re(bpy)2(CO)2][OTf]	20	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		225	1480
10.	[Re(bpy)2(CO)2][OTf]	50	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		50	535
11.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	3844	118	534
12.	[Re(bpy)2(CO)2][OTf]	100	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		38	428
13.	[Ru(bpy)2ClCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	40	67	419
14.	[Ru(bpy)2ClCO][PF6]	0.002	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	40	67	419
15.	Ru(py)-(MeNdpp)2(CO)2Cl	25	[Ru(bpy)3][PF6]	0.025	TEOA		DMF	405			380
16.	Ru(py)-(MeNdpp)2(CO)2Cl	100	[Ru(bpy)3][PF6]	0.1	TEOA		DMF	405		57.5	363
17.	[Ru(bpy)(H2O)(CO)][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	45	65	335
18.	[Ru(bpy)(H2O)(CO)][PF6]	0.002	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	45	65	335
19.	[Ru(bpy)2ClCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	36	33	296
20.	[Ru(bpy)2ClCO][PF6]	0.003	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	36	33	296
21.	Ru(dtBubpy)(CO)2Cl2	50	Molecule:100877	0.05			DMF	436	20	72	290
22.	Ru(dtBubpy)(CO)2Cl2	50	Molecule:100877	0.05	BI(OH)H	0.03	DMF	436	16	49	280
23.	[Re(bpy)2(CO)2][OTf]	200	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		24	275
24.	[Ru(bpy)2HCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	25	62	225
further results hidden...

Cat conc 0.025, TON H2 <10 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	13	8	62
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	2	4	21
3.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	7	9	40
4.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	1	2	13
5.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	4	27
6.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	8	8	34

Subtopics of "Homogeneous photocatalytic CO2 conversion"

This category has the following 3 subcategories, out of 3 total.

P

Photocatalytic CO2 conversion to CH4 (4 publications)
Photocatalytic CO2 conversion to CO (26 publications)
Photocatalytic CO2 conversion to HCOOH (18 publications)

Homogeneous photocatalytic CO2 conversion

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Subtopics of "Homogeneous photocatalytic CO2 conversion"

P

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