Homogeneous photocatalytic CO2 conversion

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The content of this topic page covers information on molecules that have been shown to be suitable for the reduction of CO₂. Currently, the information on this page is limited to information on the conversion of CO2 to CO, CH4 and CHOOH, further extension of the content is planned in the future.

-> CO2 conversion

-> -> Photocatalytic CO2 conversion

Dear reader, I am a test molecule called phenol PhOH (100617), you can call me also benzenol PhOH (100617).

TON CO >100, sorted by catalyst - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	TON CO	TON CH4	TON H2	TON HCOOH
1.	Fe(DHPP)Cl	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	139	26	15
2.	Fe(DHPP)Cl	0.0002	[Cu(PP)2][TBA]2	0.1	BIH	0.1	DMF	16109		843
3.	Fe(DHPP)Cl	0.002	Ir(ppy)3	0.2	TEA	0.36	MeCN	140
4.	Fe(DHPP)Cl	0.0006	Molecule:100932	0.02	BIH	0.06	DMF	21616
5.	Fe(DHPP)Cl	0.0002	[Cu(PP)2][TBA]2	0.1	BIH	0.01	DMF	4779		270
6.	Mn(oMesbpy)(CO)2Br	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN	208		0.5	5
7.	Mn(bpy)(CO)3Br	2	ZnTPP	0.5	TEA	0.1	MeCN	119			19
8.	[Ir(mesbpy-(PCy2)2)][BPh4]	0.02			BIH	0.2	DMA	470		15	2080
9.	[Co(pabop)][ClO4]2	0.05	Ir(ppy)3	0.2	TEA		MeCN	270
10.	Molecule:100776	2.5E-5	[Ru(phen)3][PF6]2	0.4	TEOA	300	MeCN	16896		368
11.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.05	BIH	0.1	DMF	520		0	21
12.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.05	BIH	0.1	MeCN	1336		10	34
13.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	DMF	350		1	23
14.	[Fe(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.2			MeCN	160		8	22
15.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	1879		15	48
16.	[Fe(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF	1365		0	115
17.	[Fe(qpy)(H2O)2][ClO4]2	0.02	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	2660		29	51
18.	[Fe(qpy)(H2O)2][ClO4]2	0.01	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	3087		121	35
19.	[Fe(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF	520		0	14
20.	[Fe(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	3844		118	534
21.	[Co(qpy)(H2O)2][ClO4]2	0.01	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	1875		11	18
22.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	366		15	4
23.	[Co(qpy)(H2O)2][ClO4]2	0.2	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	1262		7	23
24.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	497		5	3
further results hidden...

TON HCOOH, descending order - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	TON CO	TON H2	TON HCOOH
1.	Ni(pbi)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O			14000
2.	Ni(pbt)(pyS)2	0.004	Eosin Y	2	TEOA	0.4	H2O			13100
3.	[Ru(bpy)(py)-(MeNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	300	1897	5634
4.	[Ru(bpy)(py)-(MeNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	224	1438	4593
5.	[Ru(bpy)(py)-(tBuNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	129	505	3792
6.	[Ru(bpy)(py)-(tBuNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	129	556	3296
7.	[Re(bpy)2(CO)2][OTf]	0.01	[Ru(bpy)3][PF6]	1	TEOA		DMA		375	2750
8.	[Ir(mesbpy-(PCy2)2)][BPh4]	0.02			BIH	0.2	DMA	470	15	2080
9.	[Re(bpy)2(CO)2][OTf]	0.02	[Ru(bpy)3][PF6]	1	TEOA		DMA		225	1480
10.	[Re(bpy)2(CO)2][OTf]	0.05	[Ru(bpy)3][PF6]	1	TEOA		DMA		50	535
11.	[Fe(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	3844	118	534
12.	[Re(bpy)2(CO)2][OTf]	0.1	[Ru(bpy)3][PF6]	1	TEOA		DMA		38	428
13.	[Ru(bpy)2ClCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	40	67	419
14.	[Ru(bpy)2ClCO][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	40	67	419
15.	Ru(py)-(MeNdpp)2(CO)2Cl	0.025	[Ru(bpy)3][PF6]	0.025	TEOA		DMF			380
16.	Ru(py)-(MeNdpp)2(CO)2Cl	0.1	[Ru(bpy)3][PF6]	0.1	TEOA		DMF		57.5	363
17.	[Ru(bpy)(H2O)(CO)][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	45	65	335
18.	[Ru(bpy)(H2O)(CO)][PF6]	0.0016	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	45	65	335
19.	[Ru(bpy)2ClCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	36	33	296
20.	[Ru(bpy)2ClCO][PF6]	0.0031	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	36	33	296
21.	Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05			DMF	20	72	290
22.	Ru(dtBubpy)(CO)2Cl2	0.05	Molecule:100877	0.05	BI(OH)H	0.03	DMF	16	49	280
23.	[Re(bpy)2(CO)2][OTf]	0.2	[Ru(bpy)3][PF6]	1	TEOA		DMA		24	275
24.	[Ru(bpy)2HCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	25	62	225
further results hidden...

Cat conc 0.025, TON H2 <10 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	TON CO	TON H2	TON HCOOH
1.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	3	4	27
2.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	8	8	34
3.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	2	4	21
4.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	13	8	62
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	7	9	40
6.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	1	2	13

Subtopics of "Homogeneous photocatalytic CO2 conversion"

This topic has the following 3 subtopics, out of 3 total.

P

Photocatalytic CO2 conversion to CH4‎ (4 publications)
Photocatalytic CO2 conversion to CO‎ (22 publications)
Photocatalytic CO2 conversion to HCOOH‎ (18 publications)

Homogeneous photocatalytic CO2 conversion

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Subtopics of "Homogeneous photocatalytic CO2 conversion"

P

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