Concentration and solvent effect
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< Function-Integrated Ru Catalyst for Photochemical CO2 Reduction
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.02 |
|
0.1 |
|
|
39:1 | 20 | Xenon lamp (420 - 750) | 4 | 73 | 1 | 8 | 89.0%; 0%; 1.2%; 9.8%; 0% |
|
No | |||||||||||||||||||||||||
| 0.04 |
|
0.1 |
|
|
39:1 | 20 | Xenon lamp (420 - 750) | 4 | 58 | 1 | 3 | 93.5%; 0%; 1.6%; 4.8%; 0% |
|
No | |||||||||||||||||||||||||
| 0.08 |
|
0.1 |
|
|
39:1 | 20 | Xenon lamp (420 - 750) | 4 | 29 | 2 | 93.5%; 0%; 0%; 6.5%; 0% |
|
No | ||||||||||||||||||||||||||
| 0.04 |
|
0.1 |
|
|
39:1 | 20 | Xenon lamp (420 - 750) | 4 | 42 | 1 | 5 | 87.5%; 0%; 2.1%; 10.4%; 0% |
|
No | |||||||||||||||||||||||||
| 0.04 |
|
0.1 |
|
|
19:1 | 20 | Xenon lamp (420 - 750) | 4 | 67 | 1 | 9 | 87.0%; 0%; 1.3%; 11.7%; 0% |
|
No | |||||||||||||||||||||||||
| 0.04 |
|
0.1 |
|
|
9:1 | 20 | Xenon lamp (420 - 750) | 4 | 20 | 1 | 6 | 74.1%; 0%; 3.7%; 22.2%; 0% |
|
No |
