Homogeneous photocatalytic CO2 conversion

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TON CO >5 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Molecule:100776	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN	450 nm (LED, 100 mW.cm^-2)	16896	368
2.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN		15520	86
3.	Molecule:100968	0.2	Ru(bpy)3	0.2	BIH	0.1	MeCN		30349	1013
4.	[Ru(bpy)2HCO][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	8	8	34
5.	[Ru(bpy)2ClCO][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	13	8	62
6.	[Ru(bpy)(H2O)(CO)][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	7	9	40
7.	[Ru(bpy)(py)-(tBuNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	129	505	3792
8.	[Ru(bpy)(py)-(MeNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	224	1438	4593
9.	[Ru(bpy)(py)-(tBuNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	129	556	3296
10.	[Ru(bpy)(py)-(MeNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	300	1897	5634
11.	Ru(dppq)(tpy)(MeCN)	40			BIH	0.1	DMA	420-750	58	1	3
12.	Molecule:100941	10	Molecule:100940	1	BIH	0.1	MeCN	420	80	33
13.	Molecule:100941	10	Molecule:100940	1	BIH	0.02	MeCN	420	576	287
14.	Molecule:100941	10	Molecule:100940	1	BIH	0.02	MeCN	420	100	43
15.	[Ru(bpy)2HCO][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	21	16	107
16.	[Ru(bpy)(H2O)(CO)][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	45	65	335
17.	[Ru(bpy)2HCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	25	62	225
18.	[Ru(bpy)2ClCO][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	19	19	117
19.	[Ru(bpy)(H2O)(CO)][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	21	14	75
20.	[Ru(bpy)(H2O)(CO)][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	34	28	211
21.	[Ru(bpy)2ClCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	36	33	296
22.	[Ru(bpy)2ClCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	40	67	419
23.	[Ru(bpy)2HCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	16	29	145
24.	[Co(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	366	15	4
further results hidden...

TON HCOOH - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	[Ru(bpy)(AcMe)2][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	3	4	27
2.	Ru(bpy)2CO3	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	2	4	21
3.	[Ru(bpy)2HCO][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	8	8	34
4.	[Ru(bpy)2ClCO][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	13	8	62
5.	Ru(bpy)2Cl2	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	1	2	13
6.	[Ru(bpy)(H2O)(CO)][PF6]	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	7	9	40
7.	[Ru(bpy)(py)-(tBuNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	129	505	3792
8.	[Ru(bpy)(py)-(MeNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	224	1438	4593
9.	[Ru(bpy)(py)-(tBuNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	129	556	3296
10.	[Ru(bpy)(py)-(MeNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	300	1897	5634
11.	Ru(dppq)(tpy)(MeCN)	40			TEOA		DMA	420-750			14
12.	Ru(dppq)(tpy)(MeCN)	40			BIH	0.1	DMA	420-750	58	1	3
13.	[Ru(bpy)2HCO][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	21	16	107
14.	[Ru(bpy)(AcMe)2][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	4	44	75
15.	[Ru(bpy)(H2O)(CO)][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	45	65	335
16.	[Ru(bpy)2HCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	25	62	225
17.	Ru(bpy)2Cl2	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	3	9	26
18.	[Ru(bpy)2ClCO][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	19	19	117
19.	[Ru(bpy)(H2O)(CO)][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	21	14	75
20.	[Ru(bpy)(H2O)(CO)][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	34	28	211
21.	[Ru(bpy)2ClCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	36	33	296
22.	[Ru(bpy)2ClCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	40	67	419
23.	[Ru(bpy)(AcMe)2][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	4	12	64
24.	Ru(bpy)2CO3	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	3	11	39
further results hidden...

Cat conc 0.025, TON H2 <10 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	13	8	62
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	2	4	21
3.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	7	9	40
4.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	1	2	13
5.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	4	27
6.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	8	8	34

Solvent A not NMP - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Molecule:100776	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN
2.	Molecule:100776	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN		450 nm (LED, 100 mW.cm^-2)	16896	368
3.			[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN		450 nm (LED, 100 mW.cm^-2)
4.	Molecule:100776	0.025	[Ru(phen)3][PF6]2	0.4			MeCN		450 nm (LED, 100 mW.cm^-2)
5.	Molecule:100776	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN	Argon atmosphere	450 nm (LED, 100 mW.cm^-2)
6.	Molecule:100776	0.025			TEOA	0.3	MeCN		450 nm (LED, 100 mW.cm^-2)
7.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN			15520	86
8.	Molecule:100968	0.2	Ru(bpy)3	0.2	BIH	0.1	MeCN			30349	1013
9.	[Ru(bpy)(py)-(tBuNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA		450 W Hg lamp, K2CrO4 filter	129	505	3792
10.	[Ru(bpy)(py)-(MeNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA		450 W Hg lamp, K2CrO4 filter	224	1438	4593
11.	[Ru(bpy)(py)-(tBuNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA		450 W Hg lamp, K2CrO4 filter	129	556	3296
12.	[Ru(bpy)(py)-(MeNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA		450 W Hg lamp, K2CrO4 filter	300	1897	5634
13.	Ru(dppq)(tpy)(MeCN)	40			TEOA		DMA		420-750			14
14.	Ru(dppq)(tpy)(MeCN)	40			BIH	0.1	DMA		420-750	58	1	3
15.	Molecule:100941	10	Molecule:100940	1	BIH	0.1	MeCN		420	80	33
16.	Molecule:100941	10	Molecule:100940	1	BIH	0.02	MeCN		420	0	0
17.	Molecule:100941	10	Molecule:100940	1	BIH	0.02	MeCN		420	576	287
18.	Molecule:100941	10	Molecule:100940	1	BIH	0.02	MeCN		420	100	43
19.	Molecule:100941	10			BIH	0.02	MeCN		420	0	0
20.	Molecule:100941	10	Molecule:100940	1	BIH	0.02	MeCN		420	3.2	1.6
21.	[Co(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.3			MeCN		460 (LED)	0	1	1
22.	[Co(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	Argon atmosphere	460 (LED)	0	33	0
23.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		460 (LED)	0	2	1
24.	[Co(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		460 (LED)	366	15	4
further results hidden...

Subtopics of "Homogeneous photocatalytic CO2 conversion"

This category has the following 3 subcategories, out of 3 total.

P

Photocatalytic CO2 conversion to CH4 (4 publications)
Photocatalytic CO2 conversion to CO (26 publications)
Photocatalytic CO2 conversion to HCOOH (18 publications)

Homogeneous photocatalytic CO2 conversion

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Subtopics of "Homogeneous photocatalytic CO2 conversion"

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