Homogeneous photocatalytic CO2 conversion

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	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON H2	TON HCOOH
1.	Molecule:100968	2			BIH	0.1	MeCN		112	0
2.	Molecule:100968	2	Ru(bpy)3	0.2			MeCN		150	0
3.	Molecule:100968	2	Molecule:100970	0.2	BIH	0.1	MeCN		6710	0
4.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN	Ar	0	222
5.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN		6	0
6.	Molecule:100968	2	Molecule:100970	0.2	BIH	0.1	MeCN		6710	0
7.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN	Ar	0	222
8.	Molecule:100968	2	Ru(bpy)3	0.2			MeCN		150	0
9.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN		6	0
10.	Molecule:100968	2			BIH	0.1	MeCN		112	0
11.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		0	2	1
12.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	Argon atmosphere	0	3	1
13.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		182	0	11
14.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	Argon atmosphere	0	33	0
15.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		0	6	1
16.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3			MeCN		0	1	1
17.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN		136	43	5
18.	[Co(qpy)(H2O)2][ClO4]2	0	purpurin	2	BIH	0.1	DMF		0	0	90
19.	[Co(qpy)(H2O)2][ClO4]2	0.005	purpurin	2			DMF	Argon atmosphere	0	0	26
20.	[Co(qpy)(H2O)2][ClO4]2	0.05	purpurin	0	BIH	0.1	DMF		27	0	4
21.	[Co(qpy)(H2O)2][ClO4]2	0.005	purpurin	2	BIH	0.1	DMF	Argon atmosphere	0	226	167
22.	Co(ClO4)2	0.05	purpurin	2	BIH	0.1	DMF		0	0	3
23.	[Co(qpy)(H2O)2][ClO4]2	0.05	purpurin	2			DMF		0	0	3
24.	[Co(qpy)(H2O)2][ClO4]2	0.05	purpurin	2	BIH	0.1	DMF	Argon atmosphere	0	78	6
further results hidden...

TON CO >5 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2
1.	Molecule:100776	2.5E-5	[Ru(phen)3][PF6]2	0.4	TEOA	300	MeCN		16896		368
2.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	8000	5000	34000
3.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	108000	4000	278000
4.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	175000	19000	29000
5.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	51000	12000
6.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		5000	1000	15000
7.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		130000	29000	4900000
8.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		9000		36000
9.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	31000		320000
10.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	76000		17000
11.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	310000		33000
12.	Molecule:100968	0.2	Ru(bpy)3	0.2	BIH	0.1	MeCN		30349		1013
13.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN		15520		86
14.	Molecule:100968	2			BIH	0.1	MeCN		112		0
15.	Molecule:100968	2	Ru(bpy)3	0.2			MeCN		150		0
16.			Ru(bpy)3	0.2	BIH	0.1	MeCN		43		52
17.	Molecule:100968	0.2	Molecule:100971	0.2	BIH	0.1	MeCN		28712		6527
18.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN		15520		86
19.	Molecule:100968	0.2	Ru(bpy)3	0.2	BIH	0.1	MeCN		30349		1013
20.	Molecule:100968	2	Ir(ppy)3	0.2	BIH	0.1	MeCN		18502		141
21.	Molecule:100968	2	Molecule:100970	0.2	BIH	0.1	MeCN		6710		0
22.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN		6		0
23.	Molecule:100968	2	Molecule:100971	0.2	BIH	0.1	MeCN		12749		163
24.	Molecule:100968	2	Molecule:100970	0.2	BIH	0.1	MeCN		6710		0
further results hidden...

TON HCOOH - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON H2	TON HCOOH
1.	[Re(bpy)2(CO)2][OTf]	0.5	[Ru(bpy)3][PF6]	1	TEOA		DMA			15	115
2.	[Re(bpy)2(CO)2][OTf]	0.01	[Ru(bpy)3][PF6]	1	TEOA		DMA			375	2750
3.	[Re(bpy)2(CO)2][OTf]	0.1	[Ru(bpy)3][PF6]	1	TEOA		DMA			38	428
4.	[Re(bpy)2(CO)2][OTf]	0.05	[Ru(bpy)3][PF6]	1	TEOA		DMA			50	535
5.	[Re(bpy)2(CO)2][OTf]	1	[Ru(bpy)3][PF6]	1	TEOA		DMA			1.5	52
6.	[Re(bpy)2(CO)2][OTf]	0.2	[Ru(bpy)3][PF6]	1	TEOA		DMA			24	275
7.	[Re(bpy)2(CO)2][OTf]	0.02	[Ru(bpy)3][PF6]	1	TEOA		DMA			225	1480
8.	[Re(bpy)2(CO)2][OTf]	1			TEOA		DMA				10.3
9.	Ru(dppq)(tpy)(MeCN)	0.04			TEOA		DMA				14
10.	Ru(dppq)(tpy)(MeCN)	0.04			BIH	0.1	DMA		58	1	3
11.	Mn(oMesbpy)(CO)2Br	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN		208	0.5	5
12.	Mn(bpy)(CO)3Br	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN		50	4	157
13.	Molecule:100845	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN		164	1	65
14.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		0	2	1
15.	[Co(qpy)(H2O)2][ClO4]2	0.01	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		1875	11	18
16.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3			MeCN		114	25	25
17.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		366	15	4
18.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	Argon atmosphere	0	3	1
19.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		182	0	11
20.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		2660	23	35
21.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		0	6	1
22.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		497	5	3
23.	[Co(qpy)(H2O)2][ClO4]2	0.1	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN		466	2	22
24.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3			MeCN		0	1	1
further results hidden...

Cat conc 0.025, TON H2 <10 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	TON CO	TON H2	TON HCOOH
1.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	3	4	27
2.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	8	8	34
3.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	2	4	21
4.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	13	8	62
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	7	9	40
6.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	1	2	13

Solvent A not NMP - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2	TON HCOOH
1.	Molecule:100776	2.5E-5	[Ru(phen)3][PF6]2	0.4	TEOA	300	MeCN		16896		368
2.	Molecule:100776	2.5E-5			TEOA	300	MeCN
3.			[Ru(phen)3][PF6]2	0.4	TEOA	300	MeCN
4.	Molecule:100776	2.5E-5	[Ru(phen)3][PF6]2	0.4	TEOA	300	MeCN
5.	Molecule:100776	2.5E-5	[Ru(phen)3][PF6]2	0.4			MeCN
6.	Molecule:100776	2.5E-5	[Ru(phen)3][PF6]2	0.4	TEOA	300	MeCN	Argon atmosphere
7.	[Re(bpy)2(CO)2][OTf]	0.5	[Ru(bpy)3][PF6]	1	TEOA		DMA				15	115
8.	[Re(bpy)2(CO)2][OTf]	0.01	[Ru(bpy)3][PF6]	1	TEOA		DMA				375	2750
9.	[Re(bpy)2(CO)2][OTf]	0.1	[Ru(bpy)3][PF6]	1	TEOA		DMA				38	428
10.	[Re(bpy)2(CO)2][OTf]	0.05	[Ru(bpy)3][PF6]	1	TEOA		DMA				50	535
11.	[Re(bpy)2(CO)2][OTf]	1	[Ru(bpy)3][PF6]	1	TEOA		DMA				1.5	52
12.	[Re(bpy)2(CO)2][OTf]	0.2	[Ru(bpy)3][PF6]	1	TEOA		DMA				24	275
13.	[Re(bpy)2(CO)2][OTf]	0.02	[Ru(bpy)3][PF6]	1	TEOA		DMA				225	1480
14.	[Re(bpy)2(CO)2][OTf]	1			TEOA		DMA					10.3
15.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		10000	58000
16.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		570000
17.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	8000	5000	34000
18.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	108000	4000	278000
19.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	175000	19000	29000
20.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	51000	12000
21.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		5000	1000	15000
22.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		130000	29000	4900000
23.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		9000		36000
24.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	31000		320000
further results hidden...

Subtopics of "Homogeneous photocatalytic CO2 conversion"

This topic has the following 3 subtopics, out of 3 total.

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Photocatalytic CO2 conversion to CH4‎ (4 publications)
Photocatalytic CO2 conversion to CO‎ (22 publications)
Photocatalytic CO2 conversion to HCOOH‎ (18 publications)

Homogeneous photocatalytic CO2 conversion

Subtopics of "Homogeneous photocatalytic CO2 conversion"

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