Category:Homogeneous photocatalytic CO2 conversion

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TON CO >5 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	.	.	solvent A	.	.	additives	.	.	.	.	TON CO	.	TON CH4	TON H2	.	TON HCOOH	.	.	.
1.	Molecule:100776	2.5E-5	[Ru(phen)3][PF6]2	0.4	TEOA	300			MeCN								16896			368
2.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01			MeCN			TEA, H2O					8000		5000	34000
3.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01			MeCN			TEA					108000		4000	278000
4.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01			MeCN			TEA, H2O					175000		19000	29000
5.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01			MeCN			TEA, H2O					51000		12000
6.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA				MeCN								5000		1000	15000
7.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA				MeCN								130000		29000	4900000
8.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA				MeCN								9000			36000
9.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01			MeCN			TEA, H2O					31000			320000
10.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01			MeCN			TEA					76000			17000
11.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01			MeCN			TEA					310000			33000
12.	Molecule:100968	0.2	Ru(bpy)3	0.2	BIH	0.1			MeCN								30349			1013
13.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1			MeCN								15520			86
14.	Molecule:100968	2			BIH	0.1			MeCN								112			0
15.	Molecule:100968	2	Ru(bpy)3	0.2					MeCN								150			0
16.			Ru(bpy)3	0.2	BIH	0.1			MeCN								43			52
17.	Molecule:100968	0.2	Molecule:100971	0.2	BIH	0.1			MeCN								28712			6527
18.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1			MeCN								15520			86
19.	Molecule:100968	0.2	Ru(bpy)3	0.2	BIH	0.1			MeCN								30349			1013
20.	Molecule:100968	2	Ir(ppy)3	0.2	BIH	0.1			MeCN								18502			141
21.	Molecule:100968	2	Molecule:100970	0.2	BIH	0.1			MeCN								6710			0
22.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1			MeCN								6			0
23.	Molecule:100968	2	Molecule:100971	0.2	BIH	0.1			MeCN								12749			163
24.	Molecule:100968	2	Molecule:100970	0.2	BIH	0.1			MeCN								6710			0
further results hidden...

TON HCOOH - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	.	.	solvent A	.	.	additives	.	.	.	.	TON CO	.	TON H2	TON HCOOH	.	.	.
1.	[Re(bpy)2(CO)2][OTf]	0.5	[Ru(bpy)3][PF6]	1	TEOA				DMA										15	115
2.	[Re(bpy)2(CO)2][OTf]	0.01	[Ru(bpy)3][PF6]	1	TEOA				DMA										375	2750
3.	[Re(bpy)2(CO)2][OTf]	0.1	[Ru(bpy)3][PF6]	1	TEOA				DMA										38	428
4.	[Re(bpy)2(CO)2][OTf]	0.05	[Ru(bpy)3][PF6]	1	TEOA				DMA										50	535
5.	[Re(bpy)2(CO)2][OTf]	1	[Ru(bpy)3][PF6]	1	TEOA				DMA										1.5	52
6.	[Re(bpy)2(CO)2][OTf]	0.2	[Ru(bpy)3][PF6]	1	TEOA				DMA										24	275
7.	[Re(bpy)2(CO)2][OTf]	0.02	[Ru(bpy)3][PF6]	1	TEOA				DMA										225	1480
8.	[Re(bpy)2(CO)2][OTf]	1			TEOA				DMA											10.3
9.	Ru(dppq)(tpy)(MeCN)	0.04			BIH	0.1			DMA								58		1	3
10.	Ru(dppq)(tpy)(MeCN)	0.04			TEOA				DMA											14
11.	Mn(oMesbpy)(CO)2Br	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01			MeCN								208		0.5	5
12.	Mn(bpy)(CO)3Br	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01			MeCN								50		4	157
13.	Molecule:100845	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01			MeCN								164		1	65
14.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.3	BIH	0.1			MeCN								0		2	1
15.	[Co(qpy)(H2O)2][ClO4]2	0.01	Ru(bpy)3Cl2	0.3	BIH	0.1			MeCN								1875		11	18
16.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3					MeCN								114		25	25
17.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1			MeCN								366		15	4
18.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.2	BIH	0.1			MeCN			Argon atmosphere					0		3	1
19.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1			MeCN								182		0	11
20.	[Co(qpy)(H2O)2][ClO4]2	0.005	Ru(bpy)3Cl2	0.3	BIH	0.1			MeCN								2660		23	35
21.	[Co(qpy)(H2O)2][ClO4]2	0	Ru(bpy)3Cl2	0.2	BIH	0.1			MeCN								0		6	1
22.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3	BIH	0.1			MeCN								497		5	3
23.	[Co(qpy)(H2O)2][ClO4]2	0.1	Ru(bpy)3Cl2	0.3	BIH	0.1			MeCN								466		2	22
24.	[Co(qpy)(H2O)2][ClO4]2	0.05	Ru(bpy)3Cl2	0.3					MeCN								0		1	1
further results hidden...

Cat conc 0.025, TON H2 <10 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	.	TON CO	TON H2	TON HCOOH	.	.
1.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP		3	4	27
2.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP		8	8	34
3.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP		2	4	21
4.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP		13	8	62
5.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP		7	9	40
6.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP		1	2	13

Subtopics of "Homogeneous photocatalytic CO2 conversion"

This topic has the following 3 subtopics, out of 3 total.

P

Photocatalytic CO2 conversion to CH4‎ (4 publications)
Photocatalytic CO2 conversion to CO‎ (22 publications)
Photocatalytic CO2 conversion to HCOOH‎ (18 publications)

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Photocatalytic CO2 conversion