Photocatalytic CO2 conversion to CO
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Table of all the experiments that have a turnover number for CO greater than 100, sorted by catalyst and in descending order.
TON CO > 100
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | additives | . | . | . | TON CO | TON CH4 | TON H2 | . | . | . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1. | [Ni(bpy)-(MeNHC)2][PF6]2 | 2.0E-6 | Ir(ppy)3 | 0.1 | TEA | MeCN | 130000 | 29000 | 4900000 | ||||||||
2. | [Ni(bpy-bNHCEt)][PF6]2 | 2.0E-6 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA, H2O | 175000 | 19000 | 29000 | ||||||
3. | [Ni(bpy)-(MeNHC)2][PF6]2 | 2.0E-6 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA, H2O | 51000 | 12000 | |||||||
4. | [Ni(bpy-bNHCMe)][PF6]2 | 2.0E-6 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA, H2O | 8000 | 5000 | 34000 | ||||||
5. | [Ni(bpy)-(MeNHC)2][PF6]2 | 2.0E-6 | Ir(ppy)3 | 0.1 | BIH | 0.01 | MeCN | TEA | 108000 | 4000 | 278000 | ||||||
6. | [Ni(bpy-bNHCMe)][PF6]2 | 2.0E-6 | Ir(ppy)3 | 0.1 | TEA | MeCN | 5000 | 1000 | 15000 | ||||||||
7. | Fe(pTMAPP)Cl5 | 0.002 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | 367 | 79 | 26 | |||||||
8. | Fe(pTMAPP)Cl5 | 0.002 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | TFE | 240 | 66 | 73 | ||||||
9. | Fe(pTMAPP)Cl5 | 0.002 | [Ir(ppy)2(bpy)][PF6] | 0.2 | TEA | 0.05 | MeCN | 178 | 32 | 103 | |||||||
10. | Fe(pTMAPP)Cl5 | 0.002 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | 198 | 31 | 24 | |||||||
11. | Fe(pTMAPP)Cl5 | 0.002 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | 198 | 31 | 24 | |||||||
12. | Fe(pTMAPP)Cl5 | 0.01 | Molecule:100493 | 1 | TEA | 0.1 | DMF | TFE | 140 | 29 | 23 | ||||||
13. | Fe(DHPP)Cl | 0.002 | Ir(ppy)3 | 0.2 | TEA | 0.05 | MeCN | 139 | 26 | 15 | |||||||
14. | Fe(pTMAPP)Cl5 | 0.002 | [Ir(ppy)2(bpy)][PF6] | 0.2 | DIPEA | 0.05 | MeCN | 151 | 24 | 77 | |||||||
15. | Fe(pTMAPP)Cl5 | 0.002 | [Ir(ppy)2(bpy)][PF6] | 0.2 | TEOA | 0.05 | MeCN | 134 | 23 | 67 |
Table of all the experiments that have a turnover number for CO less than 100, sorted by catalyst.
TON CO < 100
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | . | . | solvent A | . | . | additives | . | . | . | . | TON CO | . | TON CH4 | TON H2 | TON HCOOH | . | . | . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1. | Ru(bpy)2CO3 | 0.025 | [Ir(ppy)2(bpy)][PF6] | 0.025 | TEOA | NMP | 2 | 4 | 21 | |||||||||||||||
2. | Ru(bpy)2CO3 | 0.0062 | [Ir(ppy)2(bpy)][PF6] | 0.025 | TEOA | NMP | 3 | 11 | 39 | |||||||||||||||
3. | Ru(bpy)2CO3 | 25 | [Ir(ppy)2(bpy)][PF6] | 0.025 | TEOA | NMP | 2 | 4 | 21 | |||||||||||||||
4. | Ru(bpy)2CO3 | 6.2 | [Ir(ppy)2(bpy)][PF6] | 0.025 | TEOA | NMP | 3 | 11 | 39 | |||||||||||||||
5. | Ru(dtBubpy)(CO)2Cl2 | 0.05 | Molecule:100877 | 0.05 | DMF | 20 | 72 | 290 | ||||||||||||||||
6. | Ru(dtBubpy)(CO)2Cl2 | 0.05 | Molecule:100877 | 0.05 | BI(OH)H | 0.03 | DMF | 16 | 49 | 280 | ||||||||||||||
7. | [K]2[MoO(Hqpdt)2] | 0.05 | Ru(bpy)3Cl2 | 0.5 | BIH | 0.1 | MeCN | 13 | 51 | 31 | ||||||||||||||
8. | [MoO(2Hqpdt)2][NBu4] | 0.05 | Ru(bpy)3Cl2 | 0.5 | BIH | 0.1 | MeCN | 40 | 89 | 83 | ||||||||||||||
9. | [MoO(qpdt)2][NBu4]2 | 0.05 | Ru(bpy)3Cl2 | 0.5 | BIH | 0.1 | MeCN | 73 | 670 | 80 | ||||||||||||||
10. | Fe(DHPP)Cl | 0.0002 | purpurin | 0.1 | BIH | 0.01 | DMF | 88 | 0 | |||||||||||||||
11. | Fe(DHPP)Cl | 0 | [Cu(PP)2][TBA]2 | 0.1 | BIH | 0.1 | DMF | 4.4 | 0 | |||||||||||||||
12. | Fe(DHPP)Cl | 0.002 | Molecule:100936 | 0.2 | TEA | 0.05 | MeCN | 60 | ||||||||||||||||
13. | Mn(phdk)(CO)3Br | Ru(bpy)3Cl2 | 100 | BNAH | 0.1 | DMF | 21 | 22 | ||||||||||||||||
14. | Mn(phdk)(CO)3Br | Ru(bpy)3Cl2 | 100 | DMF | 9 | 13 | ||||||||||||||||||
15. | Mn(phdk)(CO)3Br | Ru(bpy)3Cl2 | 100 | BNAH | 0.1 | MeCN | 8 | 52 | ||||||||||||||||
16. | Mn(phdk)(CO)3(MeCN) | 2 | Ru(bpy)3Cl2 | 100 | BNAH | 0.1 | MeCN | 5 | 18 | |||||||||||||||
17. | Mn(phdk)(CO)3(MeCN) | Ru(bpy)3Cl2 | 100 | BNAH | 0.1 | MeCN | 15 | 58 | ||||||||||||||||
18. | Mn(phdk)(CO)3(MeCN) | Ru(bpy)3Cl2 | 200 | BNAH | 0.1 | MeCN | 8 | 52 | ||||||||||||||||
19. | Mn(phdk)(CO)3(MeCN) | Ru(bpy)3Cl2 | 100 | BNAH | 0.1 | MeCN | 9 | 48 | ||||||||||||||||
20. | Mn(phdk)(CO)3(MeCN) | Ru(bpy)3Cl2 | 100 | BNAH | 0.1 | MeCN | 7 | 40 | ||||||||||||||||
21. | Mn(phdk)(CO)3(MeCN) | Ru(bpy)3Cl2 | 100 | BNAH | 0.1 | MeCN | 7 | 34 | ||||||||||||||||
22. | Ru(dppq)(tpy)(MeCN) | 0.04 | BIH | 0.1 | DMA | 58 | 1 | 3 | ||||||||||||||||
23. | Mn(phen)(CO)3Br | Ru(bpy)3Cl2 | 100 | BNAH | 0.1 | DMF | 17 | 4 | ||||||||||||||||
24. | Mn(CN)(bpy)(CO)3 | [Ru(dmb)3][PF6]2 | 0.5 | BNAH | 0.1 | DMF | 0.6 | 1.2 | 0.72 | |||||||||||||||
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