Photocatalytic CO2 conversion to CO

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Table of all the experiments that have a turnover number for CO greater than 100, sorted by catalyst and in descending order.

TON CO > 100

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent Aadditives...TON COTON CH4TON H2...
1.[Ni(bpy)-(MeNHC)2][PF6]22.0E-6Ir(ppy)30.1TEAMeCN130000290004900000
2.[Ni(bpy-bNHCEt)][PF6]22.0E-6Ir(ppy)30.1BIH0.01MeCNTEA, H2O1750001900029000
3.[Ni(bpy)-(MeNHC)2][PF6]22.0E-6Ir(ppy)30.1BIH0.01MeCNTEA, H2O5100012000
4.[Ni(bpy-bNHCMe)][PF6]22.0E-6Ir(ppy)30.1BIH0.01MeCNTEA, H2O8000500034000
5.[Ni(bpy)-(MeNHC)2][PF6]22.0E-6Ir(ppy)30.1BIH0.01MeCNTEA1080004000278000
6.[Ni(bpy-bNHCMe)][PF6]22.0E-6Ir(ppy)30.1TEAMeCN5000100015000
7.Fe(pTMAPP)Cl50.002Ir(ppy)30.2TEA0.05MeCN3677926
8.Fe(pTMAPP)Cl50.002Ir(ppy)30.2TEA0.05MeCNTFE2406673
9.Fe(pTMAPP)Cl50.002[Ir(ppy)2(bpy)][PF6]0.2TEA0.05MeCN17832103
10.Fe(pTMAPP)Cl50.002Ir(ppy)30.2TEA0.05MeCN1983124
11.Fe(pTMAPP)Cl50.002Ir(ppy)30.2TEA0.05MeCN1983124
12.Fe(pTMAPP)Cl50.01Molecule:100493 1TEA0.1DMFTFE1402923
13.Fe(DHPP)Cl0.002Ir(ppy)30.2TEA0.05MeCN1392615
14.Fe(pTMAPP)Cl50.002[Ir(ppy)2(bpy)][PF6]0.2DIPEA0.05MeCN1512477
15.Fe(pTMAPP)Cl50.002[Ir(ppy)2(bpy)][PF6]0.2TEOA0.05MeCN1342367

Table of all the experiments that have a turnover number for CO less than 100, sorted by catalyst.

TON CO < 100

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]..solvent A..additives....TON CO.TON CH4TON H2TON HCOOH...
1.Ru(bpy)2CO30.025[Ir(ppy)2(bpy)][PF6]0.025TEOANMP2421
2.Ru(bpy)2CO30.0062[Ir(ppy)2(bpy)][PF6]0.025TEOANMP31139
3.Ru(bpy)2CO325[Ir(ppy)2(bpy)][PF6]0.025TEOANMP2421
4.Ru(bpy)2CO36.2[Ir(ppy)2(bpy)][PF6]0.025TEOANMP31139
5.Ru(dtBubpy)(CO)2Cl20.05Molecule:100877 0.05DMF2072290
6.Ru(dtBubpy)(CO)2Cl20.05Molecule:100877 0.05BI(OH)H0.03DMF1649280
7.[K]2[MoO(Hqpdt)2]0.05Ru(bpy)3Cl20.5BIH0.1MeCN135131
8.[MoO(2Hqpdt)2][NBu4]0.05Ru(bpy)3Cl20.5BIH0.1MeCN408983
9.[MoO(qpdt)2][NBu4]20.05Ru(bpy)3Cl20.5BIH0.1MeCN7367080
10.Fe(DHPP)Cl0.0002purpurin0.1BIH0.01DMF880
11.Fe(DHPP)Cl0[Cu(PP)2][TBA]20.1BIH0.1DMF4.40
12.Fe(DHPP)Cl0.002Molecule:100936 0.2TEA0.05MeCN60
13.Mn(phdk)(CO)3BrRu(bpy)3Cl2100BNAH0.1DMF2122
14.Mn(phdk)(CO)3BrRu(bpy)3Cl2100DMF913
15.Mn(phdk)(CO)3BrRu(bpy)3Cl2100BNAH0.1MeCN852
16.Mn(phdk)(CO)3(MeCN)2Ru(bpy)3Cl2100BNAH0.1MeCN518
17.Mn(phdk)(CO)3(MeCN)Ru(bpy)3Cl2100BNAH0.1MeCN1558
18.Mn(phdk)(CO)3(MeCN)Ru(bpy)3Cl2200BNAH0.1MeCN852
19.Mn(phdk)(CO)3(MeCN)Ru(bpy)3Cl2100BNAH0.1MeCN948
20.Mn(phdk)(CO)3(MeCN)Ru(bpy)3Cl2100BNAH0.1MeCN740
21.Mn(phdk)(CO)3(MeCN)Ru(bpy)3Cl2100BNAH0.1MeCN734
22.Ru(dppq)(tpy)(MeCN)0.04BIH0.1DMA5813
23.Mn(phen)(CO)3BrRu(bpy)3Cl2100BNAH0.1DMF174
24.Mn(CN)(bpy)(CO)3[Ru(dmb)3][PF6]20.5BNAH0.1DMF0.61.20.72
further results hidden...