Photocatalytic CO2 conversion to CO

Table of all the experiments that have a turnover number for CO greater than 100, sorted by catalyst and in descending order.

TON CO > 100

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	λexc [nm]	TON CO	TON CH4	TON H2	TON HCOOH
1.	[Ni(bpy-bNHCEt)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	solar spectrum	310000		33000
2.	[Ni(bpy-bNHCEt)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	solar spectrum	175000	19000	29000
3.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	TEA		MeCN		solar spectrum	130000	29000	4900000
4.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	solar spectrum	108000	4000	278000
5.	[Ni(bimiqpr)][PF6]2	0.002	Ir(ppy)3	0.2	TEA	0.07	MeCN		solar spectrum	98000
6.	[Ni(bpy-bNHCMe)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	solar spectrum	76000		17000
7.	Molecule:100993	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN		450	65000
8.	Molecule:100957	0.0125	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN		450	51392
9.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	solar spectrum	51000	12000
10.	[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	solar spectrum	31000		320000
11.	Molecule:100968	0.2	Ru(bpy)3	0.2	BIH	0.1	MeCN			30349		1013
12.	Fe(DHPP)Cl	0.6	Molecule:100932	0.02	BIH	0.06	DMF		>400	21616
13.	Molecule:100776	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN		450 nm (LED, 100 mW.cm^-2)	16896		368
14.	Fe(DHPP)Cl	0.2	[Cu(PP)2][TBA]2	0.1	BIH	0.1	DMF		>400	16109		843
15.	Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	MeCN			15520		86
16.	[Ni(bimiqpr)][PF6]2	0.02	Ir(ppy)3	0.2	TEA	0.07	MeCN		solar spectrum	9000
17.	[Ni(bpy-bNHCEt)][PF6]2	0.002	Ir(ppy)3	0.1	TEA		MeCN		solar spectrum	9000		36000
18.	[Ni(bpy-bNHCMe)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	solar spectrum	8000	5000	34000
19.	Molecule:100949	10	4CzIPN	0.1	TEA	0.28	DMF		420-650	6320
20.	[Ni(bpy-bNHCMe)][PF6]2	0.002	Ir(ppy)3	0.1	TEA		MeCN		solar spectrum	5000	1000	15000
21.	Fe(DHPP)Cl	0.2	[Cu(PP)2][TBA]2	0.1	BIH	0.01	DMF		>400	4779		270
22.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		460 (LED)	3844		118	534
23.	[Fe(qpy)(H2O)2][ClO4]2	10	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		460 (LED)	3087		121	35
24.	[Fe(qpy)(H2O)2][ClO4]2	20	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		460 (LED)	2660		29	51
further results hidden...

Table of all the experiments that have a turnover number for CO less than 100, sorted by catalyst.

TON CO < 100

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	2	4	21
2.	Ru(bpy)2CO3	0.0062	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	3	11	39
3.	Ru(bpy)2CO3	25	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	2	4	21
4.	Ru(bpy)2CO3	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	3	11	39
5.	Ru(dtBubpy)(CO)2Cl2	50	Molecule:100877	0.05			DMF	436	20	72	290
6.	Ru(dtBubpy)(CO)2Cl2	50	Molecule:100877	0.05	BI(OH)H	0.03	DMF	436	16	49	280
7.	[K]2[MoO(Hqpdt)2]	50	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	400	13	51	31
8.	[MoO(2Hqpdt)2][NBu4]	50	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	400	40	89	83
9.	[MoO(qpdt)2][NBu4]2	50	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	400	73	670	80
10.	Fe(DHPP)Cl	0	[Cu(PP)2][TBA]2	0.1	BIH	0.1	DMF	>400	4.4	0
11.	Fe(DHPP)Cl	0.2	purpurin	0.1	BIH	0.01	DMF	>400	88	0
12.	Fe(DHPP)Cl	2	Molecule:100936	0.2	TEA	0.05	MeCN		60
13.	Mn(phdk)(CO)3Br	100	Ru(bpy)3Cl2	100			DMF	480	9		13
14.	Mn(phdk)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	480	8		52
15.	Mn(phdk)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	DMF	480	21		22
16.	Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	500	7		40
17.	Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	457	7		34
18.	Mn(phdk)(CO)3(MeCN)	200	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	480	5		18
19.	Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	480	15		58
20.	Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	200	BNAH	0.1	MeCN	480	8		52
21.	Mn(phdk)(CO)3(MeCN)	100	Ru(bpy)3Cl2	100	BNAH	0.1	MeCN	480	9		48
22.	Ru(dppq)(tpy)(MeCN)	40			BIH	0.1	DMA	420-750	58	1	3
23.	Mn(phen)(CO)3Br	100	Ru(bpy)3Cl2	100	BNAH	0.1	DMF	480	17		4
24.	Mn(CN)(bpy)(CO)3	1000	[Ru(dmb)3][PF6]2	1	BNAH	0.1	DMF	470	2.3	0.37	9.5
further results hidden...

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