Molecule:100843: Difference between revisions
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{{Molecule | {{Molecule | ||
|abbrev=Ir(ppy)3 | |||
|trivialname=Tris(2-phenylpyridinato-C2,N)iridium(III) | |||
|molecular_role=photosensitizer | |||
|cid=11388194 | |cid=11388194 | ||
|iupacName=iridium(3+);2-phenylpyridine | |iupacName=iridium(3+);2-phenylpyridine | ||
|molecularMass=655.15995 | |molecularMass=655.15995 | ||
|molecularFormula=C<sub>33</sub>H<sub>24</sub>IrN<sub>3</sub> | |molecularFormula=C<sub>33</sub>H<sub>24</sub>IrN<sub>3</sub> | ||
|synonyms=Tris(2-phenylpyridinato-C2,N)iridium(III)$Ir(ppy)3$Tris(2-phenylpyridinato)iridium(III)$Tris(2-phenylpyridinato)iridium(III) (purified by sublimation)$tris(2-(pyridin-2-yl)phenyl)iridium$TRIS(2-(PYRIDIN-2-YL)PHENYL)IRIDIUM$MFCD12022527$fac-Tris(2-phenylpyridine)iridium(III)$SCHEMBL294298$BCP07959 | |||
|synonyms= | |||
|cas=94928-86-6 | |cas=94928-86-6 | ||
|hasVendors=true | |hasVendors=true | ||
|moleculeKey=NSABRUJKERBGOU-UHFFFAOYSA-N | |moleculeKey=NSABRUJKERBGOU-UHFFFAOYSA-N | ||
|molOrRxn= | |molOrRxn= | ||
-INDIGO- | -INDIGO-01102415372D | ||
0 0 0 0 0 0 0 0 0 0 0 V3000 | 0 0 0 0 0 0 0 0 0 0 0 V3000 | ||
| Line 105: | Line 105: | ||
M V30 END CTAB | M V30 END CTAB | ||
M END | M END | ||
|smiles=C1C=N2[Ir+3]3(N4C(C5[C-]3=CC=CC=5)=CC=CC=4)3([C-]4C(C5C=CC=CN=53)=CC=CC=4)[C-]3=CC=CC=C3C2=CC=1 | |smiles=C1C=N2[Ir+3]3(N4C(C5[C-]3=CC=CC=5)=CC=CC=4)3([C-]4C(C5C=CC=CN=53)=CC=CC=4)[C-]3=CC=CC=C3C2=CC=1 | ||
|inchi=1S/3C11H8N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-6,8-9H;/q3*-1;+3 | |inchi=1S/3C11H8N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-6,8-9H;/q3*-1;+3 | ||
| Line 112: | Line 111: | ||
|height=200 | |height=200 | ||
|float=none | |float=none | ||
|logP= | |||
|parent= | |parent= | ||
}} | }} | ||
Latest revision as of 11:45, 21 November 2025
| Properties | |
|---|---|
| CID | 11388194 |
| CAS | 94928-86-6 |
| IUPAC-Name | iridium(3+);2-phenylpyridine |
| Abbreviation | Ir(ppy)3 |
| Trivialname | Tris(2-phenylpyridinato-C2,N)iridium(III) |
| Exact mass | 655.15995 |
| Molecular formula | C33H24IrN3 |
| LogP | n/a |
| Has vendors | true |
| Molecular role | photosensitizer |
| Synonyms | Tris(2-phenylpyridinato-C2,N)iridium(III), Ir(ppy)3, Tris(2-phenylpyridinato)iridium(III), Tris(2-phenylpyridinato)iridium(III) (purified by sublimation), tris(2-(pyridin-2-yl)phenyl)iridium, TRIS(2-(PYRIDIN-2-YL)PHENYL)IRIDIUM, MFCD12022527, fac-Tris(2-phenylpyridine)iridium(III), SCHEMBL294298, BCP07959 |
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Molecule is used on following pages
topic
- Photocatalytic CO2 conversion to CO
- Homogeneous photocatalytic CO2 conversion
- Photocatalytic CO2 conversion to HCOOH
- Photocatalytic CO2 conversion to CH4
publication
- Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4
- Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction
- Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy
- Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center
- Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction
- Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst
- Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis
- Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex
- Visible-light-driven methane formation from CO2 with a molecular iron catalyst
investigation
- Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy/photocatalytic CO2 conversion under different conditions
- Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction/Results Co2+ experiments taken from SI
- Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction/CO2 Reduction under diverse conditions with diverse sensitizers
- Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex/Table 1
- A molecular noble metal-free system for efficient visible light-driven reduction of CO2 to CO/table 1
- Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis/Photocatalytic reduction of CO2: conditions optimization
- Visible-light-driven methane formation from CO2 with a molecular iron catalyst/Table 1
- Visible-light-driven methane formation from CO2 with a molecular iron catalyst/Table 2 CO gas
- Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center/Table 1
- Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst/photocatalytic conversion of CO2 to CO
- Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction/Photocatalytic CO2 reduction under varied conditions
- Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4/Results for different electron donors and proton donors
other
Molecule roles
| Investigation type | Photosensitizer |
|---|---|
| Photocatalytic CO2 conversion experiments |
|
| Cyclic Voltammetry experiments |  |
| Absorption Emission Spectroscopy experiments | |
| Ultraviolett Visuell experiments | |
