Homogeneous photocatalytic CO2 conversion

Scope of this topic and related important content

The content of this topic page covers information on homogeneous approaches that are relevant for the reduction of CO₂. Currently, the information on this page is limited to information on the conversion of CO2 to CO, CH4 and CHOOH, further extension of the content is planned in the future. To get the right context and preceding information, reading the higher level topics ->CO2 conversion and ->Photocatalytic CO2 conversion might be helpful.

Distinction from other articles within the topic ->Photocatalytic CO2 conversion

TON CO >100, sorted by catalyst - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON CH4	TON H2	TON HCOOH
1.	Fe(DHPP)Cl	2	Ir(ppy)3	0.2	TEA	0.36	MeCN		140
2.	Fe(DHPP)Cl	0.6	Molecule:100932	0.02	BIH	0.06	DMF	>400	21616
3.	Fe(DHPP)Cl	0.2	[Cu(PP)2][TBA]2	0.1	BIH	0.01	DMF	>400	4779		270
4.	Fe(DHPP)Cl	2	Ir(ppy)3	0.2	TEA	0.05	MeCN	> 420	139	26	15
5.	Fe(DHPP)Cl	0.2	[Cu(PP)2][TBA]2	0.1	BIH	0.1	DMF	>400	16109		843
6.	Mn(oMesbpy)(CO)2Br	50	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN	436	208		0.5	5
7.	Mn(bpy)(CO)3Br	2000	ZnTPP	0.5	TEA	0.1	MeCN	xenon lamp	119			19
8.	[Ir(mesbpy-(PCy2)2)][BPh4]	20			BIH	0.2	DMA	>400	470		15	2080
9.	[Co(pabop)][ClO4]2	50	Ir(ppy)3	0.2	TEA		MeCN	>460	270
10.	Molecule:100776	0.025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3	MeCN	450 nm (LED, 100 mW.cm^-2)	16896		368
11.	[Fe(qpy)(H2O)2][ClO4]2	20	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	2660		29	51
12.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.2			MeCN	460 (LED)	160		8	22
13.	[Fe(qpy)(H2O)2][ClO4]2	10	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	3087		121	35
14.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.2	BIH	0.1	DMF	460 (LED)	350		1	23
15.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF	460 (LED)	520		0	14
16.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	3844		118	534
17.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	1879		15	48
18.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.05	BIH	0.1	DMF	460 (LED)	520		0	21
19.	[Fe(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.05	BIH	0.1	MeCN	460 (LED)	1336		10	34
20.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF	460 (LED)	1365		0	115
21.	[Co(qpy)(H2O)2][ClO4]2	50	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	460 (LED)	497		5	3
22.	[Co(qpy)(H2O)2][ClO4]2	10	Ru(bpy)3Cl2	0.3	BIH	0.1	MeCN	460 (LED)	1875		11	18
23.	[Co(qpy)(H2O)2][ClO4]2	5	purpurin	2	BIH	0.1	DMF	460 (LED)	790		11	78
24.	[Co(qpy)(H2O)2][ClO4]2	50	purpurin	2	BIH	0.1	DMF	460 (LED)	197		1	9
further results hidden...

TON HCOOH, descending order - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	Ni(pbi)(pyS)2	4	Eosin Y	2	TEOA	0.4	H2O				14000
2.	Ni(pbt)(pyS)2	4	Eosin Y	2	TEOA	0.4	H2O				13100
3.	[Ru(bpy)(py)-(MeNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	300	1897	5634
4.	[Ru(bpy)(py)-(MeNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	224	1438	4593
5.	[Ru(bpy)(py)-(tBuNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	129	505	3792
6.	[Ru(bpy)(py)-(tBuNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA	450 W Hg lamp, K2CrO4 filter	129	556	3296
7.	[Re(bpy)2(CO)2][OTf]	10	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		375	2750
8.	[Ir(mesbpy-(PCy2)2)][BPh4]	20			BIH	0.2	DMA	>400	470	15	2080
9.	[Re(bpy)2(CO)2][OTf]	20	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		225	1480
10.	[Re(bpy)2(CO)2][OTf]	50	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		50	535
11.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN	460 (LED)	3844	118	534
12.	[Re(bpy)2(CO)2][OTf]	100	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		38	428
13.	[Ru(bpy)2ClCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	40	67	419
14.	[Ru(bpy)2ClCO][PF6]	0.002	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	40	67	419
15.	Ru(py)-(MeNdpp)2(CO)2Cl	25	[Ru(bpy)3][PF6]	0.025	TEOA		DMF	405			380
16.	Ru(py)-(MeNdpp)2(CO)2Cl	100	[Ru(bpy)3][PF6]	0.1	TEOA		DMF	405		57.5	363
17.	[Ru(bpy)(H2O)(CO)][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	45	65	335
18.	[Ru(bpy)(H2O)(CO)][PF6]	0.002	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	45	65	335
19.	[Ru(bpy)2ClCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	36	33	296
20.	[Ru(bpy)2ClCO][PF6]	0.003	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	36	33	296
21.	Ru(dtBubpy)(CO)2Cl2	50	Molecule:100877	0.05			DMF	436	20	72	290
22.	Ru(dtBubpy)(CO)2Cl2	50	Molecule:100877	0.05	BI(OH)H	0.03	DMF	436	16	49	280
23.	[Re(bpy)2(CO)2][OTf]	200	[Ru(bpy)3][PF6]	1	TEOA		DMA	405		24	275
24.	[Ru(bpy)2HCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP	400 - 700	25	62	225
further results hidden...

Cat conc 0.025, TON H2 <10 - please enter description -

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	solvent A	λexc [nm]	TON CO	TON H2	TON HCOOH
1.	[Ru(bpy)2ClCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	13	8	62
2.	Ru(bpy)2CO3	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	2	4	21
3.	[Ru(bpy)(H2O)(CO)][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	7	9	40
4.	Ru(bpy)2Cl2	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	1	2	13
5.	[Ru(bpy)(AcMe)2][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	3	4	27
6.	[Ru(bpy)2HCO][PF6]	0.025	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA	NMP	400 - 700	8	8	34

Dear reader, I am a test molecule called phenol PhOH (100617), you can call me also benzenol PhOH (100617).

Subtopics of "Homogeneous photocatalytic CO2 conversion"

This category has the following 3 subcategories, out of 3 total.

P

Photocatalytic CO2 conversion to CH4 (4 publications)
Photocatalytic CO2 conversion to CO (26 publications)
Photocatalytic CO2 conversion to HCOOH (18 publications)

Homogeneous photocatalytic CO2 conversion

Scope of this topic and related important content

Distinction from other articles within the topic ->Photocatalytic CO2 conversion

Subtopics of "Homogeneous photocatalytic CO2 conversion"

P

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