Photocatalytic reduction of CO2: conditions optimization

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05			MeCN						CO2					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05			MeCN						CO2					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05			MeCN						CO2					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05			MeCN	H2O					CO2					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05			MeCN	H2O					CO2					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05			MeCN	H2O					CO2					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05			MeCN						CO2					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05			MeCN						CO					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05			MeCN				TFE	0.5	CO					> 420	47																n/a			Yes
Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05			MeCN				TFE	0.5	CO					> 420	102																n/a			Yes