Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy/photocatalytic CO2 conversion under different conditions

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100951	2.5	Molecule:100952	0.005	Molecule:100861	0.05			MeCN	H2O		4:1							35	400	4	2750	687														n/a		TON and TOF calc. for PS	No
Molecule:100951	2.5	Molecule:100950	0.005	Molecule:100861	0.05			MeCN	H2O		4:1							31	400	4	6510	1630														n/a		TON and TOF calc. for PS	No
Molecule:100951	2.5	Molecule:100953	0.005	Molecule:100861	0.05			MeCN	H2O		4:1							33	400	4	8820	2205														n/a		TON and TOF calc. for PS	No
Molecule:100951	2.5	Ir(ppy)3	0.005	Molecule:100861	0.05			MeCN	H2O		4:1							33	400	4	7380	1845														n/a		TON and TOF calc. for PS	No
Molecule:100951	2.5			Molecule:100861	0.05			MeCN	H2O		4:1							26	400	4	0	0														n/a			No
Molecule:100951	0.05	Molecule:100950	0.5	Molecule:100861	0.05			MeCN	H2O		4:1							38	400	4	61	15														n/a		TON and TOF calc. for PS TON for cat: 6080 TOF for cat: 1520	No
		Molecule:100950	0.5	Molecule:100861	0.05			MeCN	H2O		4:1							36	400	4	0	0														n/a			No
Molecule:100951	0.05	Molecule:100950	0.05	Molecule:100861	0.05			MeCN	H2O		4:1							37	400	4	710	178														n/a			No
Molecule:100951	0.05	Molecule:100950	0.005	Molecule:100861	0.05			MeCN	H2O		4:1							29	400	4	860	215														n/a			No
Molecule:100951	0.005	Molecule:100950	0.005	Molecule:100861	0.05			MeCN	H2O		4:1							27	400	4	0	0														n/a			No