Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst/photocatalytic conversion of CO2 to CO

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Fe(DHPP)Cl	0.002	Ir(ppy)3	0.2	TEA	0.36			MeCN						CO2						55	140		93													n/a	93		Yes
Fe(DHPP)Cl	0.002	Molecule:100936	0.2	TEA	0.36			MeCN						CO2						45	40		100													n/a	100		No
Fe(DHPP)Cl	0.002	Molecule:100936	0.2	TEA	0.05			MeCN						CO2						45	60		100													n/a	100		Yes