Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4/Results for different electron donors and proton donors

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Ni(bpy)-(MeNHC)2][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA		CO2					solar spectrum	72																n/a		test	Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA, H2O		CO2					solar spectrum	72																n/a			Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.000002	Ir(ppy)3	0.1	TEA				MeCN						CO2					solar spectrum	72																n/a			Yes
[Ni(bpy-bNHCEt)][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA		CO2					solar spectrum	72																n/a			Yes
[Ni(bpy-bNHCEt)][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA, H2O		CO2					solar spectrum	72																n/a			Yes
[Ni(bpy-bNHCEt)][PF6]2	0.000002	Ir(ppy)3	0.1	TEA				MeCN						CO2					solar spectrum	72																n/a			Yes
[Ni(bpy-bNHCMe)][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA		CO2					solar spectrum	72																n/a			Yes
[Ni(bpy-bNHCMe)][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA, H2O		CO2					solar spectrum	72																n/a			Yes
[Ni(bpy-bNHCMe)][PF6]2	0.000002	Ir(ppy)3	0.1	TEA				MeCN						CO2					solar spectrum	72																n/a			Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA, H2O							solar spectrum	72																n/a		Atmosphere of 1:1 CO2/H2	Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA 5% (v/v), H2O 2% (v/v)		CO					solar spectrum	72																n/a			Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.000002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA 5% (v/v), H2O 2% (v/v)							solar spectrum	72																n/a		Atmosphere of 1:1 CO/H2	Yes