Selective and Efficient Photocatalytic CO2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst/photocatalytic conversion of CO2 to CO: Difference between revisions

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|irr time=55
|irr time=55
|TON CO=140
|TON CO=140
|Φ CO=93
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
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|irr time=45
|irr time=45
|TON CO=40
|TON CO=40
|Φ CO=100
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
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|irr time=45
|irr time=45
|TON CO=60
|TON CO=60
|Φ CO=100
|include=Yes
|include=Yes
}}
}}
}}
}}

Latest revision as of 15:59, 17 May 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(DHPP)Cl

0.002

Ir(ppy)3

0.2

TEA

0.36


MeCN



CO2 55 140 n/a


Yes

Fe(DHPP)Cl

0.002

Molecule:100936

0.2

TEA

0.36


MeCN



CO2 45 40 n/a


No

Fe(DHPP)Cl

0.002

Molecule:100936

0.2

TEA

0.05


MeCN



CO2 45 60 n/a


Yes