Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4/Results for different electron donors and proton donors

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Ni(bpy-bNHCMe)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA, H2O		CO2					solar spectrum	72	8000			5000			34000									17.0%; 10.6%; 72.3%; 0%; 0%			Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA 5% (v/v), H2O 2% (v/v)		CO					solar spectrum	72				10000			58000									0%; 14.7%; 85.3%; 0%; 0%			Yes
[Ni(bpy-bNHCMe)][PF6]2	0.002	Ir(ppy)3	0.1	TEA				MeCN						CO2					solar spectrum	72	5000			1000			15000									23.8%; 4.8%; 71.4%; 0%; 0%			Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA		CO2					solar spectrum	72	108000			4000			278000									27.7%; 1.0%; 71.3%; 0%; 0%		test	Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA, H2O		CO2					solar spectrum	72	31000						320000									8.8%; 0%; 91.2%; 0%; 0%			Yes
[Ni(bpy-bNHCEt)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA, H2O		CO2					solar spectrum	72	175000			19000			29000									78.5%; 8.5%; 13.0%; 0%; 0%			Yes
[Ni(bpy-bNHCEt)][PF6]2	0.002	Ir(ppy)3	0.1	TEA				MeCN						CO2					solar spectrum	72	9000						36000									20.0%; 0%; 80.0%; 0%; 0%			Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	TEA				MeCN						CO2					solar spectrum	72	130000			29000			4900000									2.6%; 0.6%; 96.9%; 0%; 0%			Yes
[Ni(bpy-bNHCMe)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA		CO2					solar spectrum	72	76000						17000									81.7%; 0%; 18.3%; 0%; 0%			Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA 5% (v/v), H2O 2% (v/v)							solar spectrum	72				570000												n/a		Atmosphere of 1:1 CO/H2	Yes
[Ni(bpy)-(MeNHC)2][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA, H2O							solar spectrum	72	51000			12000												81.0%; 19.0%; 0%; 0%; 0%		Atmosphere of 1:1 CO2/H2	Yes
[Ni(bpy-bNHCEt)][PF6]2	0.002	Ir(ppy)3	0.1	BIH	0.01			MeCN				TEA		CO2					solar spectrum	72	310000						33000									90.4%; 0%; 9.6%; 0%; 0%			Yes
Molecule:100534	0.08		0.4																		34000															n/a