Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction/Photocatalytic CO2 reduction under varied conditions: Difference between revisions
From ChemWiki
< Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
(Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100650 |cat conc=0.1 |PS=Molecule:100626 |PS conc=0.1 |e-D=Molecule...") |
m (Victor.larignon moved page Photocatalytic CO2 reduction under varied conditions to Photocatalytic CO2 reduction under varied conditions) |
||
| (7 intermediate revisions by 3 users not shown) | |||
| Line 1: | Line 1: | ||
{{Photocatalytic CO2 conversion experiments | {{Photocatalytic CO2 conversion experiments | ||
|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100823 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 13: | Line 13: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100827 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 25: | Line 25: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100823 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 37: | Line 37: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100827 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 49: | Line 49: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100823 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 60: | Line 60: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100823 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 72: | Line 72: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100823 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 84: | Line 84: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100823 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 94: | Line 94: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100823 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|solvent A=Molecule:100530 | |solvent A=Molecule:100530 | ||
| Line 104: | Line 104: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100823 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule: | |PS=Molecule:100843 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
Latest revision as of 10:57, 13 February 2024
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.1 | 0.1 | 0.011 |
|
|
|
TEA | solar spectrum | 10.6 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.1 | 0.1 | 0.011 |
|
|
|
TEA | solar spectrum | 0.1 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.1 | 0.1 | 0.011 |
|
|
|
TEA | solar spectrum | 9 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.1 | 0.1 | 0.011 |
|
|
|
TEA | solar spectrum | 0.5 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.1 | 0.1 | 0.011 |
|
|
|
solar spectrum | 1.8 | n/a |
|
Yes | |||||||||||||||||||||||||||||
| 0.1 | 0.1 | 0.011 |
|
|
|
proton sponge | solar spectrum | 5.6 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.1 | 0.1 | 0.011 |
|
|
|
TfOH | solar spectrum | 0.9 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.1 |
|
0.011 |
|
|
|
TEA | solar spectrum | 0.6 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.1 | 0.1 |
|
|
|
|
TEA | solar spectrum | 0.3 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.1 | 0.1 | 0.011 |
|
|
|
N2 | solar spectrum | 0.2 | n/a |
|
Yes |
