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Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH/Photocatalytic CO2 reduction with the Mn complexes under various conditions.# 027399c045df01ebf8c547779c05b
catContains the molecule used as the catalyst in an experiment or molecular process. ᵖ
100 µM +
e-DContains the molecule used as the electron donor in an experiment or molecular process. ᵖ
Electron donor concentrationContains the concentration of an electron donor of a molecule used in an experiment or molecular process.
0.1 M +
Excitation wavelengthContains the excitation wavelength of an experiment or molecular process.
480 +
PSContains the molecule used as the photosensitizer in an experiment or molecular process. ᵖ
Photosensitizer concentrationContains the concentration of an Photosensitizer of a molecule used in an experiment or molecular process.
100 mM +
Selectivity CH4Contains selectivity of an experiment or molecular process regarding CH4.
0 % +
Selectivity COContains selectivity of an experiment or molecular process regarding CO.
75.8 % +
Selectivity H2Contains selectivity of an experiment or molecular process regarding H2.
0 % +
Selectivity HCOOHContains selectivity of an experiment or molecular process regarding HCOOH.
24.2 % +
Selectivity MeOHContains selectivity of an experiment or molecular process regarding MeOH.
0 % +
Solvent AContains the molecule used as a solvent A in an experiment or molecular process.
Solvent BContains the molecule used as a solvent B in an experiment or molecular process.
Solvent ratioContains a string describing the solvent ratio of an experiment or molecular process.
4:1 +
Turnover number COContains the turnover number of the product CO of an experiment or molecular process. The turnover number (TON) is the number of moles of substrate that a mole of catalyst can convert before becoming inactivated. https://doi.org/10.1021/acscatal.6b00183.
47 TON +
Turnover number HCOOHContains the turnover number of the product HCOOH of an experiment or molecular process. The turnover number (TON) is the number of moles of substrate that a mole of catalyst can convert before becoming inactivated. https://doi.org/10.1021/acscatal.6b00183.
15 TON +
Has subobject"Has subobject" is a predefined property representing a <a target="_blank" rel="nofollow noreferrer noopener" class="external text" href="https://www.semantic-mediawiki.org/wiki/Help:Container">container</a> construct and is provided by <a target="_blank" rel="nofollow noreferrer noopener" class="external text" href="https://www.semantic-mediawiki.org/wiki/Help:Special_properties">Semantic MediaWiki</a>.
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