Results Co2+ experiments taken from SI
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< Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 2 | 0.2 | 0.1 | 1 |
|
|
CO2 | 1.5 | 2.83 | 7.73 | n/a |
|
in 5 mL solvent | |||||||||||||||||||||||||||
| 2 | 0.2 | 0.1 | 1 |
|
|
CO2 | 1.5 | 2.03 | 8.53 | n/a |
|
in 5 mL solvent | |||||||||||||||||||||||||||
| 2 | 0.2 | 0.05 | 1 |
|
|
CO2 | 1.5 | 4.27 | 10.92 | n/a |
|
in 5 mL solvent | |||||||||||||||||||||||||||
| 2 | 0.2 | 0.05 | 1 |
|
|
CO2 | 1.5 | 10.78 | 2.2 | n/a |
|
in 5 mL solvent | |||||||||||||||||||||||||||
| 2 | 0.2 | 0.05 | 1 |
|
|
CO2 | 1.5 | 6.27 | 3.15 | n/a |
|
in 5 mL solvent | |||||||||||||||||||||||||||
| 2 | 0.2 | 0.05 | 1 |
|
|
CO2 | 1.5 | 2 | 0.133 | n/a |
|
in 5 mL solvent | |||||||||||||||||||||||||||
| 2 | 0.2 | 0.05 | 0.5 |
|
|
CO2 | 1.5 | 0.217 | 0.97 | n/a |
|
in 5 mL solvent | |||||||||||||||||||||||||||
| 2 | 0.2 | 0.05 | 0.1 |
|
|
CO2 | 1.5 | 0.23 | 1.2 | n/a |
|
in 5 mL solvent | |||||||||||||||||||||||||||
| 2 | 0.2 | 0.05 | 0.1 |
|
|
CO2 | 1.5 | 0.3 | 0.483 | n/a |
|
in 5 mL solvent |
