Table 2 Co catalyst testing

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< Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction
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investigation
Molecular process, Photocatalytic CO2 conversion experiments
"Molecule:" can not be assigned to a declared number type with value 1009792."Molecule:" can not be assigned to a declared number type with value 1009819.
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100969

2

Ru(bpy)3

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90 Molecule:100973 464 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90 Molecule:100974 512 n/a


in 5 mL solvent

Molecule:100969

2

Ir(ppy)3

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 Molecule:100975 655 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 Molecule:100976 Molecule:1009792 n/a


in 5 mL solvent true

Molecule:100969

2

Ru(bpy)3

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 Molecule:100977 Molecule:1009819 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

PhOH

1

MeCN



CO2 90 Molecule:100978 8 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

PhOH

0.5

MeCN



CO2 90 Molecule:100979 58 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

Molecule:100972

0.1

MeCN



CO2 90 Molecule:100980 72 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

Molecule:1006Molecule:100981

0.1

MeCN



CO2 90 Molecule:100981 29 n/a


in 5 mL solvent