Photocatalytic CO2 reduction with varying concentrations of cat and PS

From ChemWiki
< Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
Revision as of 10:03, 17 May 2024 by Laura (talk | contribs) (Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100671 |cat conc=0.0005 |PS=Molecule:100932 |PS conc=0.0005 |e-D=Molecule:100508 |e-D conc=0.06 |solvent A=Molecule:100529 |λexc=> 400 |TON CO=3174 |include=No }}{{Photocatalytic CO2 conversion |catalyst=Molecule:100671 |cat conc=0.001 |PS=Molecule:100932 |PS conc=0.001 |e-D=Molecule:100508 |e-D conc=0.06 |solvent A=Molecule:100529 |λexc=> 400 |TON CO=3587 |inclu...")
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)

investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(DHPP)Cl

0.0005

Molecule:100932

0.0005

BIH

0.06


DMF



> 400 3174 n/a


No

Fe(DHPP)Cl

0.001

Molecule:100932

0.001

BIH

0.06


DMF



> 400 3587 n/a


No

Fe(DHPP)Cl

0.002

Molecule:100932

0.002

BIH

0.06


DMF



> 400 3817 n/a


No

Fe(DHPP)Cl

0.005

Molecule:100932

0.005

BIH

0.06


DMF



> 400 4978 n/a


No

Fe(DHPP)Cl

0.01

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No