Photocatalytic reduction of CO2 with different photosensitizers

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< Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
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investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(DHPP)Cl

0.0006

Molecule:100930

0.02

BIH

0.06


DMF



>400 48 2395 1510 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100958

0.02

BIH

0.06


DMF



>400 48 2738 69 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100959

0.02

BIH

0.06


DMF



>400 48 3551 593 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100931

0.02

BIH

0.06


DMF



>400 48 8360 1614 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100932

0.02

BIH

0.06


DMF



>400 48 21616 4028 n/a


Yes

Fe(DHPP)Cl

0.0006

Molecule:100933

0.02

BIH

0.06


DMF



>400 48 907 93 n/a


No