photocatalytic reduction of CO2 to CO
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< Merging an organic TADF photosensitizer and a simple terpyridine–Fe(iii) complex for photocatalytic CO2 reduction
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.01 | 0.05 | 0.28 |
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3:2 | CO2 | 420-650 | 3 | 2250 | 99.3 | n/a |
99.3 |
Yes | ||||||||||||||||||||||||||
0.01 | 0.01 | 0.28 |
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|
CO2 | 420-650 | 3 | 133 | n/a |
|
No | |||||||||||||||||||||||||||
0.01 | 0.05 | 0.28 |
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|
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CO2 | 420-650 | 3 | 244 | n/a |
|
No | |||||||||||||||||||||||||||
0.01 | 0.1 | 0.28 |
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|
|
CO2 | 420-650 | 3 | 246 | n/a |
|
No | |||||||||||||||||||||||||||
0.01 | 0.05 | 0.28 |
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|
|
CO2 | 420-650 | 3 | 6 | n/a |
|
No |