photocatalytic CO2 conversion
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< Water-Assisted Highly Efficient Photocatalytic Reduction of CO2 to CO with Noble Metal-Free Bis(terpyridine)iron(II) Complexes and an Organic Photosensitizer
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.01 | 0.05 | 0.28 |
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3:2 | CO2 | 420-650 | 2 | 6320 | 127 | n/a |
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Yes | ||||||||||||||||||||||||||
0.01 | 0.05 | 0.28 |
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3:2 | CO2 | 420-650 | 2 | 2780 | n/a |
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No | |||||||||||||||||||||||||||
0.01 | 0.05 | 0.28 |
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3:2 | CO2 | 420-650 | 2 | 4500 | n/a |
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No | |||||||||||||||||||||||||||
0.01 | 0.05 | 0.28 |
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|
3:2 | CO2 | 420-650 | 2 | 19 | n/a |
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No | |||||||||||||||||||||||||||
0.01 | 0.05 | 0.28 |
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|
3:2 | CO2 | 420-650 | 2 | 992 | n/a |
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No |