Photocatalytic CO2 reduction: best results
From ChemWiki
< Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
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0.0002 | 0.1 | 0.01 |
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>400 | 7 | 88 | 45 | 0 | n/a |
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Yes | ||||||||||||||||||||||||||
0.0002 | 0.1 | 0.01 |
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>400 | 7 | 4779 | 1356 | 270 | 94.7%; 0%; 5.3%; 0%; 0% |
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Yes | ||||||||||||||||||||||||||
0.0002 | 0.1 | 0.1 |
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>400 | 23 | 16109 | 7650 | 843 | 95.0%; 0%; 5.0%; 0%; 0% |
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Yes | ||||||||||||||||||||||||||
0 | 0.1 | 0.1 |
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>400 | 1 | 4.4 | 4.3 | 0 | n/a |
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Yes |