Photoreduction of CO2

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< Ir(tpy)(bpy)Cl as a Photocatalyst for CO2 Reduction under Visible-Light Irradiation
Revision as of 15:08, 9 February 2024 by Victor.larignon (talk | contribs) (Victor.larignon moved page Photoreduction of CO2 to Photoreduction of CO2)

investigation
Molecular process, Photocatalytic CO2 conversion experiments
"Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property."Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property."Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property."Molecule:100865" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[Ir(bpy)(tpy)Cl][PF6]2

0.1


TEOA


MeCN

TEOA


5:1 Molecule:100865 410 - 750 nm 24 2 1 20 8.7%; 0%; 4.3%; 87.0%; 0%


Yes

[Ir(dmbpy)(tpy)Cl][PF6]2

0.1


TEOA


MeCN

TEOA


5:1 Molecule:100865 410 - 750 nm 24 5 3 9 29.4%; 0%; 17.6%; 52.9%; 0%


Yes

[Ir(dnbpy)(tpy)Cl][PF6]2

0.1


TEOA


MeCN

TEOA


5:1 Molecule:100865 410 - 750 nm 24 3 1 5 33.3%; 0%; 11.1%; 55.6%; 0%


Yes

Molecule:100869

0.1


TEOA


MeCN

TEOA


5:1 Molecule:100865 410 - 750 nm 8 0 1 7 0%; 0%; 12.5%; 87.5%; 0%


Yes