Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light/Table 3 - CV

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analyte anl conc [mM] E0/0 [eV] E0/0 type E1/2 [eV] *Ered [eV] *Eox [eV] *Redox type Ered1 [eV] Ered2 [eV] Ered3 [eV] Eox1 [eV] Eox2 [eV] Eox3 [eV] solvent solvent vol [ml] electrolyte electrolyte purity el conc [M] int ref comp scan rate [mV/s] scan number potential window scan dir gas T [°C] condition [nm] WE WE SA [mm²] CE RE Details include

Molecule:100610

0, -2.11;

MeCN

TBABF4

0.1


100 glassy carbon 0.79 platinum Ag/AgNO3 in MeCN Yes

Ru(bpy)2CO3

0.45, -1.97;

MeCN

TBABF4

0.1


100 glassy carbon 0.79 platinum Ag/AgNO3 in MeCN Yes

[Ru(bpy)2ClCO][PF6]

1.22, -1.75;

MeCN


0.1


100 0.79 Yes