Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light/Table 3 - CV

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analyte anl conc [mM] reduction potential oxidation potential solvent solvent vol [ml] electrolyte electrolyte purity el conc [M] int ref comp scan rate [mv s-1] scan number potential window scan dir gas T [° C] condition [nm] WE WE surface area [mm²] CE RE Details include

Molecule:100610

0,-2.11

MeCN

TBABF4

0.1


100 glassy carbon 0.79 platinum Ag/AgNO3 in MeCN Yes

Ru(bpy)2CO3

0.45,-1.97

MeCN

TBABF4

0.1


100 glassy carbon 0.79 platinum Ag/AgNO3 in MeCN Yes

[Ru(bpy)2ClCO][PF6]

1.22,-1.75

MeCN


0.1


100 0.79 Yes