Photocatalytic CO2 Reduction by 1 (2 μM) in CO2-Saturated Aqueous CH3CN Solutions

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O		100/0								450		2332						106			1370						61.2%; 0%; 2.8%; 36.0%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O		95/5								450		6228						304			2441						69.4%; 0%; 3.4%; 27.2%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O		90/10								450		14691						283			1097						91.4%; 0%; 1.8%; 6.8%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O		85/15								450		15822						220			1147						92.0%; 0%; 1.3%; 6.7%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O		80/20								450		18989						227			1215						92.9%; 0%; 1.1%; 5.9%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEOA	0.15	MeCN	H2O		80/20	Hg							450		19646						226			415						96.8%; 0%; 1.1%; 2.0%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O		100/0								450		183						9			419						30.0%; 0%; 1.5%; 68.6%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O		95/5								450		612						202			51						70.8%; 0%; 23.4%; 5.9%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O		90/10								450		515						253			46						63.3%; 0%; 31.1%; 5.7%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O		85/15								450		3171						498			179						82.4%; 0%; 12.9%; 4.7%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O		80/20								450		6331						264			179						93.5%; 0%; 3.9%; 2.6%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1	TEA	0.15	MeCN	H2O		80/20	Hg							450		6286						304			97						94.0%; 0%; 4.5%; 1.5%; 0%			No