BIH + TEOA under Various Conditions
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< Light-Driven Reduction of CO2 to CO in Water with a Cobalt Molecular Catalyst and an Organic Sensitizer
Molecular process, Photocatalytic CO2 conversion experiments
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
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0.002 | 0.2 | 0.1 |
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85/15 | 450 | 2332 | 106 | 1370 | 61.2%; 0%; 2.8%; 36.0%; 0% |
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No | |||||||||||||||||||||||||||
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0.2 | 0.1 |
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85/15 | 450 | 0 | 0 | 0 | n/a |
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No | |||||||||||||||||||||||||||
0.002 |
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0.1 |
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85/15 | 450 | 0 | 0 | 0 | n/a |
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No | |||||||||||||||||||||||||||
0.002 | 0.2 |
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85/15 | 450 | 950 | 86 | 316 | 70.3%; 0%; 6.4%; 23.4%; 0% |
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No | |||||||||||||||||||||||||||
0.002 | 0.2 | 0.1 |
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450 | 107 | 7 | 5 | 89.9%; 0%; 5.9%; 4.2%; 0% |
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No | |||||||||||||||||||||||||||
0.002 | 0.2 | 0.1 |
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85/15 | Argon atmosphere | 450 | 0 | 7 | 0 | n/a |
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No | ||||||||||||||||||||||||||
0.005 | 0.2 | 0.1 |
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85/15 | 450 | 0 | 159 | 0 | n/a |
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No | |||||||||||||||||||||||||||
0.002 | 0.2 | 0.1 |
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85/15 | Hg (0.1 mL) | 450 | 1880 | 255 | 1973 | 45.8%; 0%; 6.2%; 48.0%; 0% |
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No |