Optimizations of conditions for Fe(qpy)(H2O)2(ClO4)2
From ChemWiki
< Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.05 | 0.02 | 0.1 |
|
|
|
460 (LED) | 12 | 520 | 97 | 0 | 0 | 14 | 3 | 97.4%; 0%; 0%; 2.6%; 0% |
100 |
No | |||||||||||||||||||||||
| 0.05 | 0.02 | 0.1 |
|
|
|
Argon atmosphere | 460 (LED) | 12 | 0 | 0 | 3 | 37 | 21 | 63 | 0%; 0%; 12.5%; 87.5%; 0% |
100 |
No | ||||||||||||||||||||||
| 0 | 0.02 | 0.1 |
|
|
|
460 (LED) | 12 | 0 | 0 | 139 | 100 | 0 | 0 | n/a |
100 |
No | |||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
|
460 (LED) | 12 | 520 | 96 | 0 | 0 | 21 | 4 | 96.1%; 0%; 0%; 3.9%; 0% |
100 |
No | |||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
|
Argon atmosphere | 460 (LED) | 12 | 0 | 0 | 0 | 0 | 8 | 100 | n/a |
100 |
No | ||||||||||||||||||||||
| 0 | 0.05 | 0.1 |
|
|
|
460 (LED) | 12 | 0 | 0 | 0 | 0 | 10 | 100 | n/a |
100 |
No | |||||||||||||||||||||||
| 0.05 | 0.2 | 0.1 |
|
|
|
460 (LED) | 12 | 350 | 94 | 1 | 0 | 23 | 6 | 93.6%; 0%; 0.3%; 6.1%; 0% |
100 |
No | |||||||||||||||||||||||
| 0.05 | 0.2 | 0.1 |
|
|
|
Argon atmosphere | 460 (LED) | 12 | 0 | 0 | 54 | 73 | 20 | 27 | 0%; 0%; 73.0%; 27.0%; 0% |
100 |
No | ||||||||||||||||||||||
| 0.05 | 0 | 0.1 |
|
|
|
460 (LED) | 12 | 0 | 0 | 0 | 0 | 24 | 100 | n/a |
100 |
No | |||||||||||||||||||||||
| 0.05 | 0.02 | 0.1 |
|
|
|
460 (LED) | 12 | 0 | 0 | 0 | 0 | 8 | 100 | n/a |
100 |
No | |||||||||||||||||||||||
| 0.005 | 0.02 | 0.1 |
|
|
|
460 (LED) | 12 | 1365 | 92 | 0 | 0 | 115 | 8 | 92.2%; 0%; 0%; 7.8%; 0% |
100 |
No | |||||||||||||||||||||||
| 0.005 | 0.02 | 0.1 |
|
|
|
Argon atmosphere | 460 (LED) | 12 | 0 | 0 | 52 | 37 | 88 | 63 | 0%; 0%; 37.1%; 62.9%; 0% |
100 |
No |
