Table 1

From ChemWiki
< Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction
investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[Re(bpy)(CO)3(MeCN)][PF6]

0.05

Molecule:100731

0.05



DMF

TEOA


5:1 436 1 27 0.53 n/a

0.53

Yes

Molecule:100748

0.05

Molecule:100731

0.05



DMF

TEOA


5:1 436 15 98 n/a


Yes

Molecule:100748

0.05

Molecule:100732

0.05



DMF

TEOA


5:1 436 1 22 0.61 n/a

0.61

Yes

Molecule:100748

0.05

Molecule:100732

0.05



DMF

TEOA


5:1 436 15 71 n/a


Yes


Molecule:100732

0.05



DMF

TEOA


5:1 436 1 6 n/a


Yes


Molecule:100732

0.05



DMF

TEOA


5:1 436 15 8 n/a


Yes

Molecule:100748

0.05

Molecule:100733

0.05



DMF

TEOA


5:1 436 1 20 0.60 n/a

0.6

Yes

Molecule:100748

0.05

Molecule:100733

0.05



DMF

TEOA


5:1 436 15 32 n/a


Yes

Molecule:100748

0.05

Molecule:100734

0.05



DMF

TEOA


5:1 436 1 11 0.60 n/a

0.6

Yes

Molecule:100748

0.05

Molecule:100734

0.05



DMF

TEOA


5:1 436 15 48 n/a


Yes