Table 1
From ChemWiki
< Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.05 | 0.05 |
|
|
|
5:1 | 436 | 1 | 27 | 0.53 | n/a |
0.53 |
Yes | |||||||||||||||||||||||||||
0.05 | 0.05 |
|
|
|
5:1 | 436 | 15 | 98 | n/a |
|
Yes | ||||||||||||||||||||||||||||
0.05 | 0.05 |
|
|
|
5:1 | 436 | 1 | 22 | 0.61 | n/a |
0.61 |
Yes | |||||||||||||||||||||||||||
0.05 | 0.05 |
|
|
|
5:1 | 436 | 15 | 71 | n/a |
|
Yes | ||||||||||||||||||||||||||||
|
0.05 |
|
|
|
5:1 | 436 | 1 | 6 | n/a |
|
Yes | ||||||||||||||||||||||||||||
|
0.05 |
|
|
|
5:1 | 436 | 15 | 8 | n/a |
|
Yes | ||||||||||||||||||||||||||||
0.05 | 0.05 |
|
|
|
5:1 | 436 | 1 | 20 | 0.60 | n/a |
0.6 |
Yes | |||||||||||||||||||||||||||
0.05 | 0.05 |
|
|
|
5:1 | 436 | 15 | 32 | n/a |
|
Yes | ||||||||||||||||||||||||||||
0.05 | 0.05 |
|
|
|
5:1 | 436 | 1 | 11 | 0.60 | n/a |
0.6 |
Yes | |||||||||||||||||||||||||||
0.05 | 0.05 |
|
|
|
5:1 | 436 | 15 | 48 | n/a |
|
Yes |