Table 1

From ChemWiki
< Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study
Revision as of 09:35, 28 June 2023 by ChN (talk | contribs)

investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100614

0.002

Molecule:100493

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 103 25 80.5%; 0%; 19.5%; 0%; 0%


Yes

Molecule:100614

0.002

Molecule:100761

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 88 12 88.0%; 0%; 12.0%; 0%; 0%


Yes

Molecule:100614

0.002

Molecule:100762

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 115 n/a


Yes

Molecule:100614

0.002

Molecule:100763

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 112 12 90.3%; 0%; 9.7%; 0%; 0%


Yes

Molecule:100614

0.002

Molecule:100764

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 32 57 36.0%; 0%; 64.0%; 0%; 0%


Yes

Molecule:100614

0.002

Molecule:100765

0.2

BIH

0.005


MeCN



TFE 0.1 > 400 21 89 n/a


Yes