Photocatalytic reduction of CO2, best TON

From ChemWiki
< Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid
Revision as of 09:15, 19 May 2023 by ChN (talk | contribs) (Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100756 |cat conc=0.02 |e-D=Molecule:100508 |e-D conc=0.2 |solvent A...")
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)

investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[Ir(mesbpy-(PCy2)2)][BPh4]

0.02


BIH

0.2


DMA

H2O


9:1 >400 145 470 15 2080 18.3%; 0%; 0.6%; 81.1%; 0%


Yes