Photocatalytic CO2 reduction with the Mn complexes under various conditions.

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Mn(phdk)(CO)3Br		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								480	16	8									52						13.3%; 0%; 0%; 86.7%; 0%			Yes
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								480	24	15									58						20.5%; 0%; 0%; 79.5%; 0%			Yes
Mn(phdk)(CO)3(MeCN)		Ru(bpy)3	100	BNAH	0.1			MeCN	TEOA		4:1								480	16	9									48						15.8%; 0%; 0%; 84.2%; 0%			Yes