Table 1
From ChemWiki
< Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 100 | 0.1 |
|
|
4:1 | 480 | 16 | 8 | 52 | 13.3%; 0%; 0%; 86.7%; 0% |
|
Yes | ||||||||||||||||||||||||||||
| 100 | 0.1 |
|
|
4:1 | 480 | 24 | 15 | 58 | 20.5%; 0%; 0%; 79.5%; 0% |
|
Yes | ||||||||||||||||||||||||||||
| 100 | 0.1 |
|
|
4:1 | 480 | 16 | 9 | 48 | 15.8%; 0%; 0%; 84.2%; 0% |
|
Yes |
