Conditions optimizations for photocatalytic reduction of CO2

From ChemWiki
< Photocatalytic CO2 Reduction under Visible-Light Irradiation by Ruthenium CNC Pincer Complexes
Revision as of 15:21, 24 January 2023 by ChN (talk | contribs) (Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100655 |cat conc=0.01 |PS=Molecule:100659 |PS conc=0.05 |e-D=Molecu...")
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)

investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100655

0.01

[Ru(dmb)3][PF6]2

0.05

BI(OH)H

0.1


DMA

TEOA


4:1 450 W HG lamp, K2CrO4 filter 24 129 556 3296 3.2%; 0%; 14.0%; 82.8%; 0%


Yes

Molecule:100656

0.01

[Ru(dmb)3][PF6]2

0.05

BI(OH)H

0.1


DMA

TEOA


4:1 450 W HG lamp, K2CrO4 filter 24 224 1438 4593 3.6%; 0%; 23.0%; 73.4%; 0%


Yes

Molecule:100657

0.01

[Ru(dmb)3][PF6]2

0.05

BI(OH)H

0.1


DMA

TEOA


4:1 450 W HG lamp, K2CrO4 filter 24 129 505 3792 2.9%; 0%; 11.4%; 85.7%; 0%


Yes

Molecule:100658

0.01

[Ru(dmb)3][PF6]2

0.05

BI(OH)H

0.1


DMA

TEOA


4:1 450 W HG lamp, K2CrO4 filter 24 300 1897 5634 3.8%; 0%; 24.2%; 71.9%; 0%


Yes


[Ru(dmb)3][PF6]2

0.05

BI(OH)H

0.1


DMA

TEOA


4:1 450 W HG lamp, K2CrO4 filter 24 0 0 0 n/a


No

Molecule:100658

0.01


BI(OH)H

0.1


DMA

TEOA


4:1 450 W HG lamp, K2CrO4 filter 24 8.9 87 0 9.3%; 0%; 90.7%; 0%; 0%


No

Molecule:100568

0.01

[Ru(dmb)3][PF6]2

0.05



DMA

TEOA


4:1 450 W HG lamp, K2CrO4 filter 24 0 20 0 n/a


No

Molecule:100658

0.01

[Ru(dmb)3][PF6]2

0.05

BI(OH)H

0.1


DMA

TEOA


4:1 450 W HG lamp, K2CrO4 filter 24 0 307 0 n/a


No

Molecule:100658

0.01

[Ru(dmb)3][PF6]2

0.05

BI(OH)H

0.1


DMA

TEOA


4:1 under dark 0 0 0 n/a


No