inv0

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Fe1	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	987	41.1	not reported	not reported			187	not reported		not reported		not reported				84.1%; 0%; 15.9%; 0%; 0%				"not reported" is not a number.
Fe2	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	1318	54.9	not reported	not reported			243	not reported		not reported		not reported				84.4%; 0%; 15.6%; 0%; 0%				"not reported" is not a number.
Fe3	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	847	35.3	not reported	not reported			205	not reported		not reported		not reported				80.5%; 0%; 19.5%; 0%; 0%				"not reported" is not a number.
Fe4	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	1265	52.7	not reported	not reported			133	not reported		not reported		not reported				90.5%; 0%; 9.5%; 0%; 0%				"not reported" is not a number.
Fe2	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	4	311	77.7	not reported	not reported			51	not reported		not reported		not reported				85.9%; 0%; 14.1%; 0%; 0%				"not reported" is not a number.
Fe2	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	48	1578	32.9	not reported	not reported			296	not reported		not reported		not reported				84.2%; 0%; 15.8%; 0%; 0%				"not reported" is not a number.
Fe2	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	96	1593	16.6	not reported	not reported			300	not reported		not reported		not reported				84.2%; 0%; 15.8%; 0%; 0%				"not reported" is not a number.
Fe2	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	0	MeCN	H2O	not reported	not reported	not reported	0	CO2		not reported		35	462	24	2	not reported	not reported	not reported			22	not reported		not reported		not reported				8.3%; 0%; 91.7%; 0%; 0%				"not reported" is not a number.
Fe2	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	1352	56.3	not reported	not reported			285	not reported		not reported		not reported				82.6%; 0%; 17.4%; 0%; 0%				"not reported" is not a number.
Fe2	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	661	27.5	not reported	not reported			191	not reported		not reported		not reported				77.6%; 0%; 22.4%; 0%; 0%				"not reported" is not a number.
Fe2	50	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	621	25.8	not reported	not reported			77	not reported		not reported		not reported				89.0%; 0%; 11.0%; 0%; 0%				"not reported" is not a number.
Fe2	25	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	2086	86.9	not reported	not reported			123	not reported		not reported		not reported				94.4%; 0%; 5.6%; 0%; 0%				"not reported" is not a number.
Fe2	12.5	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	4259	177.4	not reported	not reported			276	not reported		not reported		not reported				93.9%; 0%; 6.1%; 0%; 0%				"not reported" is not a number.
Fe2	6.25	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	10168	423.7	not reported	not reported			862	not reported		not reported		not reported				92.2%; 0%; 7.8%; 0%; 0%				"not reported" is not a number.
Fe2	3.12	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	not reported	not reported	not reported	not reported	CO2		not reported		35	462	24	23138	964.1	not reported	not reported			2177	not reported		not reported		not reported				91.4%; 0%; 8.6%; 0%; 0%				"not reported" is not a number.