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investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe1

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 24 987 41.1 not reported not reported 187 not reported not reported not reported not reported 84.1%; 0%; 15.9%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 24 1318 54.9 not reported not reported 243 not reported not reported not reported not reported 84.4%; 0%; 15.6%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe3

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 24 847 35.3 not reported not reported 205 not reported not reported not reported not reported 80.5%; 0%; 19.5%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe4

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 24 1265 52.7 not reported not reported 133 not reported not reported not reported not reported 90.5%; 0%; 9.5%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 4 311 77.7 not reported not reported 51 not reported not reported not reported not reported 85.9%; 0%; 14.1%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 48 1578 32.9 not reported not reported 296 not reported not reported not reported not reported 84.2%; 0%; 15.8%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 96 1593 16.6 not reported not reported 300 not reported not reported not reported not reported 84.2%; 0%; 15.8%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 0 v/v 35 not reported not reported 308 K 462 24 2 not reported not reported not reported 22 not reported not reported not reported not reported 8.3%; 0%; 91.7%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 10 v/v 35 not reported not reported 308 K 462 24 1352 56.3 not reported not reported 285 not reported not reported not reported not reported 82.6%; 0%; 17.4%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 30 v/v 35 not reported not reported 308 K 462 24 661 27.5 not reported not reported 191 not reported not reported not reported not reported 77.6%; 0%; 22.4%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

50.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 50 v/v 35 not reported not reported 308 K 462 24 621 25.8 not reported not reported 77 not reported not reported not reported not reported 89.0%; 0%; 11.0%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

25.0

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 24 2086 86.9 not reported not reported 123 not reported not reported not reported not reported 94.4%; 0%; 5.6%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

12.5

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 24 4259 177.4 not reported not reported 276 not reported not reported not reported not reported 93.9%; 0%; 6.1%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

6.25

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 24 10168 423.7 not reported not reported 862 not reported not reported not reported not reported 92.2%; 0%; 7.8%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

3.12

[Ru(bpy)3]2+

0.3

BIH

0.11

not reported

Molecule:100616

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 24 23138 964.1 not reported not reported 2177 not reported not reported not reported not reported 91.4%; 0%; 8.6%; 0%; 0%


<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

Fe2

3.12

[Ru(bpy)3]2+

0.3

BIH

0.11

H2O

not reported

MeCN

H2O


CO2 7.5 v/v 35 not reported not reported 308 K 462 4 9754 2438 8.24 not reported not reported not reported not reported not reported not reported n/a

8.24

<ul><li>"not reported" is not a number.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>