inv0

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investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[[[Fe(bpzphen)(H2O)2](BF4)2 (Fe1) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 987 41.1 h-1 187 84.1%; 0%; 15.9%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzphen)(H2O)2](BF4)2 (Fe1)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 1318 54.9 h-1 243 84.4%; 0%; 15.6%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 847 35.3 h-1 205 80.5%; 0%; 19.5%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 1265 52.7 h-1 133 90.5%; 0%; 9.5%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 4 h 311 77.7 h-1 51 85.9%; 0%; 14.1%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 48 h 1578 32.9 h-1 296 84.2%; 0%; 15.8%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 96 h 1593 16.6 h-1 300 84.2%; 0%; 15.8%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


MeCN



CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 2 < 0.1 h-1 22 8.3%; 0%; 91.7%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

10 %

90:10 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 1352 56.3 h-1 285 82.6%; 0%; 17.4%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

30 %

70:30 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 661 27.5 h-1 191 77.6%; 0%; 22.4%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

50 %

50:50 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 621 25.8 h-1 77 89.0%; 0%; 11.0%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

25.0 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 2086 86.9 h-1 123 94.4%; 0%; 5.6%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

12.5 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 4259 177.4 h-1 276 93.9%; 0%; 6.1%; 0%; 0%


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

6.25 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


MeCN

H2O

H2O

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 10 168 423.7 h-1 862 7.5 % n/a

7.5

<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

3.12 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M


MeCN

H2O

H2O

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 23 138 964.1 h-1 2177 7.5 % n/a

7.5

<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzphen)(H2O)2](BF4)2 (Fe1) ]]

3.25 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M

4.8 % (462 nm)

Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 4 h n/a


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzphen)(H2O)2](BF4)2 (Fe1)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

3.25 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M

H2O

7.5 %

MeCN

H2O


92.5:7.5 (v/v) CO2-saturated CO2 absorbed photon flux 2.16 × 10^-8 einstein s^-1 35 °C 462 nm (blue LED strip) 4 h 9754 2438 h-1 7.6 % (462 nm) n/a

7.6

<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"%" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>

[[[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3) ]]

3.25 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M

3.8 % (462 nm)

Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 4 h n/a


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>

[[[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4) ]]

3.25 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

0.11 M

7.3 % (462 nm)

Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 4 h n/a


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>

[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]

50 μM

[[[Ru(bpy)3]2+ ]]

0.3 mM

BIH

27.5 mM


Molecule:100616

MeCN

H2O

7.5 %

92.5:7.5 (v/v) CO2-saturated CO2 35 °C 462 nm (blue LED strip) 24 h 221 n/a


<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>