Time profile in DMF
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< An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.2 | 0.2 |
|
|
4:1 | 405 nm | 0 | 0 | 0 | n/a |
|
No | ||||||||||||||||||||||||||||
0.2 | 0.2 |
|
|
4:1 | 405 nm | 8 | 1 | 12.5 | 93 | 0%; 0%; 7.4%; 92.6%; 0% |
93 |
No | |||||||||||||||||||||||||||
0.2 | 0.2 |
|
|
4:1 | 405 nm | 12 | 2.5 | 19.5 | 89 | 0%; 0%; 11.4%; 88.6%; 0% |
89 |
No | |||||||||||||||||||||||||||
0.2 | 0.2 |
|
|
4:1 | 405 nm | 24 | 4.5 | 50.5 | 95 | 0%; 0%; 8.2%; 91.8%; 0% |
95 |
No | |||||||||||||||||||||||||||
0.2 | 0.2 |
|
|
4:1 | 405 nm | 48 | 6 | 59.5 | 91 | 0%; 0%; 9.2%; 90.8%; 0% |
91 |
No | |||||||||||||||||||||||||||
0.2 | 0.2 |
|
|
4:1 | 405 nm | 72 | 8.5 | 69.25 | 89 | 0%; 0%; 10.9%; 89.1%; 0% |
89 |
No |