photocatalytic CO2 conversion

From ChemWiki
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100949

0.01

4CzIPN

0.05

TEA

0.28


DMF

H2O


3:2 CO2 420-650 2 6320 127 n/a


Yes

Molecule:100948

0.01

4CzIPN

0.05

TEA

0.28


DMF

H2O


3:2 CO2 420-650 2 2780 n/a


No

Molecule:100947

0.01

4CzIPN

0.05

TEA

0.28


DMF

H2O


3:2 CO2 420-650 2 4500 n/a


No

Molecule:100949

0.01

Ru(bpy)3

0.05

TEA

0.28


DMF

H2O


3:2 CO2 420-650 2 19 n/a


No

Molecule:100949

0.01

Ru(bpy)3

0.05

TEA

0.28


MeCN

H2O


3:2 CO2 420-650 2 992 n/a


No