Solvent effect study between DMA DMF and acetonitrile
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< An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 1.75 | 12.5 | 87 | 0%; 0%; 12.3%; 87.7%; 0% |
87 |
No | |||||||||||||||||||||||||||
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 2 | 15 | 88 | 0%; 0%; 11.8%; 88.2%; 0% |
88 |
No | |||||||||||||||||||||||||||
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 1.5 | 2.5 | 63 | 0%; 0%; 37.5%; 62.5%; 0% |
63 |
No | |||||||||||||||||||||||||||
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 1.5 | 2.5 | 63 | 0%; 0%; 37.5%; 62.5%; 0% |
63 |
No | |||||||||||||||||||||||||||
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 1.5 | 2.5 | 63 | 0%; 0%; 37.5%; 62.5%; 0% |
63 |
No | |||||||||||||||||||||||||||
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 1.5 | 2.5 | 63 | 0%; 0%; 37.5%; 62.5%; 0% |
63 |
No | |||||||||||||||||||||||||||
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 1.5 | 2.5 | 63 | 0%; 0%; 37.5%; 62.5%; 0% |
63 |
No | |||||||||||||||||||||||||||
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 1.5 | 2.5 | 63 | 0%; 0%; 37.5%; 62.5%; 0% |
63 |
No | |||||||||||||||||||||||||||
|
|
0.8 |
|
|
4:1 | 405 nm | 24 | 1.5 | 2.5 | 63 | 0%; 0%; 37.5%; 62.5%; 0% |
63 |
No |
