Table 1
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< Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.002 | 0.2 | 0.005 |
|
|
|
TFE | 0.1 | > 400 | 21 | 103 | 25 | 80.5%; 0%; 19.5%; 0%; 0% |
|
Yes | |||||||||||||||||||||||||
0.002 | 0.2 | 0.005 |
|
|
|
TFE | 0.1 | > 400 | 21 | 88 | 12 | 88.0%; 0%; 12.0%; 0%; 0% |
|
Yes | |||||||||||||||||||||||||
0.002 | 0.2 | 0.005 |
|
|
|
TFE | 0.1 | > 400 | 21 | 115 | n/a |
|
Yes | ||||||||||||||||||||||||||
0.002 | 0.2 | 0.005 |
|
|
|
TFE | 0.1 | > 400 | 21 | 112 | 12 | 90.3%; 0%; 9.7%; 0%; 0% |
|
Yes | |||||||||||||||||||||||||
0.002 | 0.2 | 0.005 |
|
|
|
TFE | 0.1 | > 400 | 21 | 32 | 57 | 36.0%; 0%; 64.0%; 0%; 0% |
|
Yes | |||||||||||||||||||||||||
0.002 | 0.2 | 0.005 |
|
|
|
TFE | 0.1 | > 400 | 21 | 89 | n/a |
|
Yes |