Results for photocatalytic reduction of CO2
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< Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
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0.05 |
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0.25 | 0.01 |
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4:1 | 436 | 2 | 50 | 0.02 | 4 | 157 | 0.3 | 23.7%; 0%; 1.9%; 74.4%; 0% |
0.32 |
Yes | |||||||||||||||||||||||
0.05 |
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0.25 | 0.01 |
|
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4:1 | 436 | 2 | 164 | 0.33 | 1 | 65 | 0.24 | 71.3%; 0%; 0.4%; 28.3%; 0% |
0.57 |
Yes | |||||||||||||||||||||||
0.05 |
|
0.25 | 0.01 |
|
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4:1 | 436 | 2 | 208 | 0.41 | 0.5 | 5 | 0.03 | 97.4%; 0%; 0.2%; 2.3%; 0% |
0.44 |
Yes |