Table 1

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< Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production
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investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100665

0.03

Ru(bpy)3

0.5

BIH

0.1


DMA

H2O


9:1 25 450 55 713 1.42 n/a

1.42

Yes

Molecule:100665

0.03

Ru(bpy)3

0.5

BIH

0.1


DMF

H2O


9:1 25 450 n/a


No

Molecule:100665

0.03

Ru(bpy)3

0.5

BIH

0.1


DMA

H2O


9:1 25 450 n/a


No

Molecule:100665

0.03

Ru(bpy)3

0.5

BIH

0.1


MeCN

H2O


9:1 25 450 n/a


No

Molecule:100665

0.03

Ru(bpy)3

0.5

TEA

0.1


DMA

H2O


9:1 25 450 n/a


No

Molecule:100665

0.03

Ru(bpy)3

0.5

TEOA

0.1


DMA

H2O


9:1 25 450 n/a


No