photocatalytic CO2 conversion
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< Photocatalytic CO2 Reduction Mediated by Electron Transfer via the Excited Triplet State of Zn(II) Porphyrin
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
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0.05 |
|
0.05 |
|
|
|
phenol | 0.1 | CO2 | 420 nm | 40 | 910 | 8 | n/a |
8 |
No | ||||||||||||||||||||||||
0.075 |
|
0.05 |
|
|
|
phenol | 0.1 | CO2 | 420 nm | 60 | 1340 | n/a |
|
Addition of 500 equivalents (0.025 M) of BIH to the first experiment after 48 h. | No | ||||||||||||||||||||||||
0.05 |
|
0.05 |
|
|
|
CO2 | 420 nm | 48 | 520 | n/a |
|
No |