photocatalytic CO2 conversion under different conditions
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< Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
2.5 | 0.005 | 0.05 |
|
|
4:1 | 35 | 400 | 4 | 2750 | 687 | n/a |
|
TON and TOF calc. for PS | No | |||||||||||||||||||||||||
2.5 | 0.005 | 0.05 |
|
|
4:1 | 31 | 400 | 4 | 6510 | 1630 | n/a |
|
TON and TOF calc. for PS | No | |||||||||||||||||||||||||
2.5 | 0.005 | 0.05 |
|
|
4:1 | 33 | 400 | 4 | 8820 | 2205 | n/a |
|
TON and TOF calc. for PS | No | |||||||||||||||||||||||||
2.5 | 0.005 | 0.05 |
|
|
4:1 | 33 | 400 | 4 | 7380 | 1845 | n/a |
|
TON and TOF calc. for PS | No | |||||||||||||||||||||||||
2.5 |
|
0.05 |
|
|
4:1 | 26 | 400 | 4 | 0 | 0 | n/a |
|
No | ||||||||||||||||||||||||||
0.05 | 0.5 | 0.05 |
|
|
4:1 | 38 | 400 | 4 | 61 | 15 | n/a |
|
TON and TOF calc. for PS
TON for cat: 6080 TOF for cat: 1520 |
No | |||||||||||||||||||||||||
|
0.5 | 0.05 |
|
|
4:1 | 36 | 400 | 4 | 0 | 0 | n/a |
|
No | ||||||||||||||||||||||||||
0.05 | 0.05 | 0.05 |
|
|
4:1 | 37 | 400 | 4 | 710 | 178 | n/a |
|
No | ||||||||||||||||||||||||||
0.05 | 0.005 | 0.05 |
|
|
4:1 | 29 | 400 | 4 | 860 | 215 | n/a |
|
No | ||||||||||||||||||||||||||
0.005 | 0.005 | 0.05 |
|
|
4:1 | 27 | 400 | 4 | 0 | 0 | n/a |
|
No |